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復合細化變質多元鋁硅合金強化機制的研究
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淮陰工學院 機械與材料工程學院

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基金項目:

國家自然科學基金項目( (No.51701079);淮陰工學院博士科研啟動費基金(Z301B18558);江蘇省產(chǎn)學研合作項目(FZ20190349)


Study on Strengthening Mechanism of Composite Refined and Modified Multi-component Aluminum-silicon Alloy
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1.Faculty of Mechanical and Material Engineering,Huaiyin Institute of Technology,Huai’an 223003;2.China

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The National Natural Science Foundation of China (No.51701079); Doctoral Scientific Research Start-up Foundation from Huaiyin Institute of Technology, Jiangsu, China (Z301B18558);Enterprise-University-Research Institute Collaboration Project of Jiangsu Province (FZ20190349)

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    摘要:

    為改善力學性能,采用新型Al-5Ti-1B-1RE中間合金細化劑和Al-10Sr中間合金變質劑對鑄態(tài)多元鋁硅A356鋁合金及在鑄態(tài)A356鋁合金中按一定比例添加Cu、Mn、Ti等元素組成的新型鋁合金進行復合細化變質處理。采用光學顯微鏡(OM)、掃描電鏡(SEM)及能譜、透射電鏡(TEM)和電子式萬能試驗機(CSS-44100)等技術對多元鋁硅合金中的第二相粒子的形態(tài)分布特征及強化機制進行分析。結果表明:經(jīng)復合細化變質處理的A356鋁合金中的第二相粒子共晶硅相由粗大的片層狀轉變?yōu)榈湫偷睦w維狀,在軟韌相α-Al基體晶界處較均勻的析出,α-Al相晶粒尺寸顯著變小,其強化機制主要是第二相粒子共晶硅Hall-Petch晶界細晶強化;在新型鋁合金中除第二相粒子共晶硅外,還存在其它較彌散分布在晶界或晶內的第二相強化粒子,多種強化機制共同起作用,當分布在晶界上時,主要是Hall-Petch強化機制;當分布在晶內時,主要是Orowan強化機制,成為阻礙位錯運動的有效障礙,起到強化作用。

    Abstract:

    In order to improve the mechanical properties, a new Al-5Ti-1B-1RE master alloy refiner and Al-10Sr master alloy modifier were used to composite refine and modify the as-cast A356 aluminum alloy and a novel aluminum alloy composed of as-cast A356 aluminum alloy by adding Cu, Mn, Ti and other elements in a certain proportion. The morphology distribution of the second-phase particles and strengthening mechanism of the multi-component aluminum-silicon alloy were analyzed by means of OM, SEM, TEM and the electronic universal testing machine (CSS-44100).The results showed that the second-phase eutectic silicon phase in the A356 aluminum alloy transformed from coarse lamellar to typical fibrous phase after the composite refinement and modification, and precipitated uniformly at the grain boundary of the soft-tough phase α-Al matrix. The grain size of the α-Al phase decreased significantly. It was mainly Hall-Petch grain boundary fine grain strengthening mechanism. In addition to the second-phase particle eutectic silicon in the novel aluminum alloy, there were other second-phase particles which were more dispersed in the grain boundaries or intragranular. Various strengthening mechanisms worked together. When the second-phase particles were distributed on grain boundaries, it was mainly the Hall-Petch strengthening mechanism. When the second-phase particles were distributed in intragranular, it was mainly Orowan strengthening mechanism, which became an effective obstacle to dislocation movement and played a strengthening role.

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王正軍,張滿,張秋陽,呂建強.復合細化變質多元鋁硅合金強化機制的研究[J].稀有金屬材料與工程,2020,49(10):3402~3411.[Wang Zhengjun, Zhang Man, Zhang Qiuyang, Lv Jianqiang. Study on Strengthening Mechanism of Composite Refined and Modified Multi-component Aluminum-silicon Alloy[J]. Rare Metal Materials and Engineering,2020,49(10):3402~3411.]
DOI:10.12442/j. issn.1002-185X.20190818

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  • 收稿日期:2019-10-07
  • 最后修改日期:2019-12-10
  • 錄用日期:2019-12-11
  • 在線發(fā)布日期: 2020-11-04
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