1-xYbxO3-α(0.05≤x≤0.15)質(zhì)子導(dǎo)體管,獲得了較合理的合成和成型工藝參數(shù);將其作為敏感元件組裝成電化學(xué)氫傳感器對750℃鋁液進行了電動勢測量和氫含量計算,探討了管的摻Y(jié)b量、封接方式、管壁厚度、管內(nèi)氣室長度和參比氣體的流量對傳感器響應(yīng)時間、靈敏性、準(zhǔn)確性、重現(xiàn)性和電池阻抗特性的影響。結(jié)果表明:混合原料經(jīng)1400℃煅燒4h能形成較純的質(zhì)子導(dǎo)體粉體;采用較高的成型壓力(275MPa)或較長的保壓時間(3-6min)能提高質(zhì)子導(dǎo)體管的相對密度;采用倒U型式為合理的管封接方式;采用較高的摻Y(jié)b量、較薄的管壁厚度或較短氣室長度的探頭,傳感器的響應(yīng)時間可縮短至2-4min;參比氣體流量的改變對電動勢具有迅速、顯著且可逆的影響,必須進行精確測量和控制。"/>

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SrCe1-xYbxO3-α(0.05≤x≤0.15)質(zhì)子導(dǎo)體管的制備及其鋁液測氫應(yīng)用
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1.遼寧科技大學(xué);2.東北大學(xué)

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國家自然科學(xué)基金青年項目(項目號51301079);遼寧省教育廳青年項目(項目號KKSB201451004)


Preparation of SrCe1-xYbxO3-α(0.05≤x≤0.15) Proton Conductor Tubes and its Application on Determination of Hydrogen Content in Molten Aluminum
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1.University of Science and Technology LiaoNing,School of Materials and Metallurgy;2.Northeastern University,School of Materials Science and Engineering

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    摘要:

    采用固相合成法和等靜壓成型法制備了U型SrCe1-xYbxO3-α(0.05≤x≤0.15)質(zhì)子導(dǎo)體管,獲得了較合理的合成和成型工藝參數(shù);將其作為敏感元件組裝成電化學(xué)氫傳感器對750℃鋁液進行了電動勢測量和氫含量計算,探討了管的摻Y(jié)b量、封接方式、管壁厚度、管內(nèi)氣室長度和參比氣體的流量對傳感器響應(yīng)時間、靈敏性、準(zhǔn)確性、重現(xiàn)性和電池阻抗特性的影響。結(jié)果表明:混合原料經(jīng)1400℃煅燒4h能形成較純的質(zhì)子導(dǎo)體粉體;采用較高的成型壓力(275MPa)或較長的保壓時間(3-6min)能提高質(zhì)子導(dǎo)體管的相對密度;采用倒U型式為合理的管封接方式;采用較高的摻Y(jié)b量、較薄的管壁厚度或較短氣室長度的探頭,傳感器的響應(yīng)時間可縮短至2-4min;參比氣體流量的改變對電動勢具有迅速、顯著且可逆的影響,必須進行精確測量和控制。

    Abstract:

    5%, 10% and 15%Yb-doped SrCeO3-base proton conducting ceramic tubes were prepared by solid reaction. The Electromotive forces (EMF) were continuously detected by the hydrogen probes which were fabricated with the tubes in molten aluminum at 750℃. Hydrogen contents were calculated as a result. Synthesis and pressed process parameters of ceramic tubes were discussed. The effect of Yb-doped amount and assembly methods, air chamber length or bottom thickness of the probes on the response time, sensitivity, accuracy, reproducibility and impedance spectrum characteristics for the hydrogen sensors were studied. The results indicated that the mixed powders were formed purer proton conductor after calcining at 1400°C for 4 hours. The relative density of the tubes can be improved at higher pressure (275MPa) or more holding pressure time (3-6min). The response time of the sensor can be reduced to 2-4 min by using probes which had more Yb doped amount, less tube wall thickness or shorter gas compartment length with inverted U-shaped sealing method. The reference gas flow or pressure had a rapid, outstanding and reversible effect on the EMF. It is necessary to measure and control the reference gas flow or pressure for acquiring the accurate hydrogen content.

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王東,劉春明,殷錫濤. SrCe1-xYbxO3-α(0.05≤x≤0.15)質(zhì)子導(dǎo)體管的制備及其鋁液測氫應(yīng)用[J].稀有金屬材料與工程,2020,49(7):2530~2538.[Wang Dong, Liu Chunming, Yin Xitao. Preparation of SrCe1-xYbxO3-α(0.05≤x≤0.15) Proton Conductor Tubes and its Application on Determination of Hydrogen Content in Molten Aluminum[J]. Rare Metal Materials and Engineering,2020,49(7):2530~2538.]
DOI:10.12442/j. issn.1002-185X.20190638

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  • 收稿日期:2019-08-02
  • 最后修改日期:2019-08-16
  • 錄用日期:2019-08-21
  • 在線發(fā)布日期: 2020-08-31
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