: 本文采用浸沒法研究了在523K、553K573K的溫度下有無超聲作用Cu/Sn體系的溶解行為。實(shí)驗(yàn)發(fā)現(xiàn)超聲波作用下Cu絲在熔融Sn中的溶解速率是無超聲作用的6.79~24.106倍。結(jié)合有限元模擬的方法分別從超聲波空化效應(yīng)、微射流效應(yīng)和聲流效應(yīng)等角度出發(fā)解釋這一現(xiàn)象。研究結(jié)果表明,空化泡坍塌瞬間會在Cu/Sn界面的局部產(chǎn)生1500K左右的高溫,不但提高CuSn液中的固溶度極限,而且使微點(diǎn)區(qū)域Cu發(fā)生熔化;微射流效應(yīng)能減薄金屬間化合物(IMC)層厚度和改變其形貌,增加了原子擴(kuò)散的通道聲流效應(yīng)會產(chǎn)生攪拌作用,Cu/Sn固液界面前沿的溶質(zhì)Cu原子不斷推向Sn液內(nèi)部,使溶質(zhì)原子溶度一直低于飽和溶解度。綜合以上各方面的因素使得超聲波作用下固體CuSn液中溶解量和溶解速率顯著增大。"/>

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功率超聲對Cu/Sn體系溶解行為的影響
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蘭州理工大學(xué) 甘肅省有色金屬先進(jìn)加工與再利用國家重點(diǎn)實(shí)驗(yàn)室

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國家自然科學(xué)基金資助(項(xiàng)目號51465032)


Effect of Power Ultrasound on Dissolution Behavior of Cu/Sn System
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State Key Laboratory of Advanced Processing and Recycling on Non-Ferrous Metals,Lanzhou University of Technology

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    : 本文采用浸沒法研究了在523K553K573K的溫度下有無超聲作用Cu/Sn體系的溶解行為。實(shí)驗(yàn)發(fā)現(xiàn)超聲波作用下Cu絲在熔融Sn中的溶解速率是無超聲作用的6.79~24.106倍。結(jié)合有限元模擬的方法分別從超聲波空化效應(yīng)、微射流效應(yīng)和聲流效應(yīng)等角度出發(fā)解釋這一現(xiàn)象。研究結(jié)果表明,空化泡坍塌瞬間會在Cu/Sn界面的局部產(chǎn)生1500K左右的高溫,不但提高CuSn液中的固溶度極限,而且使微點(diǎn)區(qū)域Cu發(fā)生熔化微射流效應(yīng)能減薄金屬間化合物(IMC)層厚度和改變其形貌,增加了原子擴(kuò)散的通道;聲流效應(yīng)會產(chǎn)生攪拌作用,Cu/Sn固液界面前沿的溶質(zhì)Cu原子不斷推向Sn液內(nèi)部,使溶質(zhì)原子溶度一直低于飽和溶解度。綜合以上各方面的因素使得超聲波作用下固體CuSn液中溶解量和溶解速率顯著增大。

    Abstract:

    In this paper, the immersion method was used to study the dissolution behavior of Cu/Sn system with or without ultrasound at 523K, 553K and 573K.SIt is found that the dissolution rate of Cu wire in molten Sn under ultrasonic action is 6.79~24.106 times without ultrasonic effect.SCombined with the method of finite element simulation, this phenomenon is explained from the perspectives of ultrasonic cavitation effect, micro jet effect and acoustic streaming.SThe results show that the cavitation bubble collapse will produce a high temperature of about 1500K at the Cu/Sn interface, which not only increases the solid solubility limit of Cu in the Sn liquid, but also melts the Cu in the "micro-point" region; The micro jet effect can reduce the thickness of the intermetallic compound (IMC) layer and change its morphology, and increase the channel of atomic diffusion; the acoustic streaming will produce a stirring effect, and the solute Cu atom at the front of the Cu/Sn solid-liquid interface is continuously pushed to the Sn liquid.SInternally, the solute atom solubility is always lower than the saturated solubility.SCombining the above factors, the dissolved amount and dissolution rate of solid Cu in the Sn solution are significantly increased under the action of ultrasonic waves.

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俞偉元,雷震,孫學(xué)敏,吳保磊,孫軍剛.功率超聲對Cu/Sn體系溶解行為的影響[J].稀有金屬材料與工程,2020,49(8):2724~2729.[Yu Weiyuan, Lei Zhen, Sun Xuemin, Wu Baole, Sun Jungang. Effect of Power Ultrasound on Dissolution Behavior of Cu/Sn System[J]. Rare Metal Materials and Engineering,2020,49(8):2724~2729.]
DOI:10.12442/j. issn.1002-185X.20190590

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  • 收稿日期:2019-07-13
  • 最后修改日期:2019-09-19
  • 錄用日期:2019-10-11
  • 在線發(fā)布日期: 2020-09-27
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