-11 Pa.m3/s,釬縫中間層區(qū)域為CuMn基釬料凝固組織,釬料與TZM反應界面區(qū)域較窄,與Kovar合金的界面反應區(qū)域較寬,釬料中的Mn、Cu元素與Kovar合金中的Fe元素更容易相互擴散遷移發(fā)生冶金熔合反應。"/>

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CuMn基釬料對TZM與Kovar合金的釬焊研究
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中國原子能科學研究院

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Study on brazing TZM and Kovar alloy with CuMn base filler metal
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China Institute of Atomic Energy

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    摘要:

    采用研制的CuMn基釬料對TZM與Kovar合金進行了高頻真空釬焊研究。采用DTA、氦質(zhì)譜撿漏儀、激光共聚焦顯微鏡、SEM、EDS等分析測試手段,測試了釬料的熔點、對TZM與Kovar合金潤濕性,測試了釬縫的氣密性、微觀組織形貌、界面組織成份等。結(jié)果表明:在965℃時,CuMn基釬料在TZM與Kovar合金樣品上的潤濕角θ分別為30.77°和12.30°,在最大釬焊感應電流為430A時,焊料對釬縫鋪展均勻,釬縫區(qū)域無裂紋、無氣泡等缺陷,焊件氣密性測試漏率優(yōu)于6×10-11 Pa.m3/s,釬縫中間層區(qū)域為CuMn基釬料凝固組織,釬料與TZM反應界面區(qū)域較窄,與Kovar合金的界面反應區(qū)域較寬,釬料中的Mn、Cu元素與Kovar合金中的Fe元素更容易相互擴散遷移發(fā)生冶金熔合反應。

    Abstract:

    The CuMn - based filler was used to brazing TZM and Kovar alloys.By means of DTA, helium mass spectrometer, laser confocal microscope, SEM and EDS,the melting point and wettability of TZM and Kovar alloys were tested and the gas tightness, microstructure, interfacial structure composition of the welds were also tested. The results show that: At 965 ℃, the wetting Angle of Cu-Mn base solder on TZM and Kovar alloy sample is 30.77 ° and 12.30 ° respectively. When the largest induced current is 430A, the solder spread out evenly on weld and the weld areas were without crack, without defects such as bubbles. The leakage rate test of welding are better thanS6×10-11 Pa.m3/s. The middle area of the weld is CuMn metallurgical solidification organization, solder with TZM reaction interface area is relatively narrowd and with Kovar alloy interface reaction area is wider. Mn and Cu in the filler metal and Fe in Kovar alloy are more likely to diffuse and migrate to each other to form the metallurgical fusion reaction.

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魯盛會,鄭劍平,齊立君,秦 博,曲 博,王振東. CuMn基釬料對TZM與Kovar合金的釬焊研究[J].稀有金屬材料與工程,2020,49(6):2054~2058.[Lu Shenghui, Zheng Jianping, Qi Lijun, Wang Zhendong, Qin Bo, Qi Bo. Study on brazing TZM and Kovar alloy with CuMn base filler metal[J]. Rare Metal Materials and Engineering,2020,49(6):2054~2058.]
DOI:10.12442/j. issn.1002-185X.20190338

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  • 收稿日期:2019-04-19
  • 最后修改日期:2019-06-03
  • 錄用日期:2019-06-14
  • 在線發(fā)布日期: 2020-07-09
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