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Ti-55531升溫條件下球狀和片狀α生長及回溶動(dòng)力學(xué)
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1.南京工業(yè)大學(xué)材料科學(xué)與工程學(xué)院先進(jìn)材料研究院;2.中南大學(xué)粉末冶金國家重點(diǎn)實(shí)驗(yàn)室

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國家自然科學(xué)基金青年項(xiàng)目(51801101);國防基礎(chǔ)科研計(jì)劃JCKY2018414C020


Thermo-kinetic modeling for the growth/dissolution of α globes and lamella in Ti–55531 under continuous heating condition
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1.Tech Institute for Advanced Materials School of Materials Science and Engineering,Nanjing Tech University;2.State Key Laboratory of Powder Metallurgy,Central South University

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    摘要:

    本文采用升溫?zé)崤蛎浐蚐EM觀察1K/min升溫條件下組織組成為(β+球狀α)的Ti-55531合金的組織演變,發(fā)現(xiàn)組織演變?yōu)槠瑺瞀廖龀?,片狀α回溶,球狀α回溶。建立了升溫條件下片狀析出相的生長和回溶動(dòng)力學(xué)方程和球狀析出相的生長和回溶動(dòng)力學(xué)方程,模擬這兩種形貌α相的動(dòng)力學(xué)行為,并將計(jì)算結(jié)果與實(shí)驗(yàn)測(cè)試結(jié)果進(jìn)行比較。模擬結(jié)果發(fā)現(xiàn)片狀α的生長和回溶受Gibbs-Thomson效應(yīng)影響,Gibbs-Thomson效應(yīng)降低片狀α尖端的穩(wěn)定性,使得片狀α尖端在低于平衡溫度發(fā)生回溶。片狀α尖端的延長遵循體擴(kuò)散和界面擴(kuò)散混合機(jī)制控制的動(dòng)力學(xué),而側(cè)面增厚由體擴(kuò)散控制,片狀α的溶解主要受體擴(kuò)散的影響。而球狀α在低溫下生長受擴(kuò)散速率較低的β穩(wěn)定元素的體擴(kuò)散控制,高溫下回溶受較高擴(kuò)散速度Al的體擴(kuò)散控制。

    Abstract:

    The microstructure evolution of Ti-55531 alloy with (β + global α) microstructure composition under 1K/min heating condition was observed by thermal expansion and SEM, and it was found that the microstructure evolution was α lamellae precipitate, dissolute and α globes dissolute. The kinetics equations of the growth / dissolution of the lamerllar precipitate and spherical precipitate were established. The simulation results showed that the growth and dissolution of lamellar α was affected by the Gibbs-Thomson effect, which reduced the stability of α lamella tips, thus resulting in the dissolution of α lamella tips at lower than the equilibrium temperature. The elongation of the α lamella tips follows the kinetics controlled by the mixed mechanism of bulk diffusion and interfacial diffusion, while the lateral thickening is controlled by bulk diffusion, and the bulk diffusion control dissolution of α lamella. global α growth at low temperature is controlled by the volume diffusion of stable elements with a lower diffusion rate, and the solubility at high temperature is controlled by the volume diffusion of Al with a higher diffusion rate.

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陳福文,徐廣龍,周科朝,常輝,周廉. Ti-55531升溫條件下球狀和片狀α生長及回溶動(dòng)力學(xué)[J].稀有金屬材料與工程,2020,49(4):1220~1226.[CHEN Fuwen, XU Guanglong, ZHOU Kechao, CHANG Hui, ZHOU Lian. Thermo-kinetic modeling for the growth/dissolution of α globes and lamella in Ti–55531 under continuous heating condition[J]. Rare Metal Materials and Engineering,2020,49(4):1220~1226.]
DOI:10.12442/j. issn.1002-185X.20190023

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  • 收稿日期:2019-01-07
  • 最后修改日期:2019-02-25
  • 錄用日期:2019-03-15
  • 在線發(fā)布日期: 2020-05-07
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