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高壓制備CoSbS1-xSex(x=0~0.3)的熱電性能
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1.河南理工大學(xué)物理電子與信息學(xué)院;2.河南理工大學(xué);3.中華人民共和國上海海關(guān);4.河南理工大學(xué)材料科學(xué)與工程學(xué)院

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河南省自然科學(xué)基金(182300410248);河南理工大學(xué)杰出青年基金(J2016-5);中華人民共和國上海海關(guān)科研計(jì)劃項(xiàng)目(HK012-2018 HK012-2018);國家自然科學(xué)基金資助(51772076)


High Pressure Synthesis and Thermoelectric Performance of CoSbS1-xSex(x=0~0.3)
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    摘要:

    副鈷銻硫礦(CoSbS)基熱電材料,因其組成元素廉價(jià)、環(huán)境友好等優(yōu)點(diǎn),近期受到人們的廣泛關(guān)注。但由于其具有較高的熱導(dǎo)率限制了熱電性能,此外,常規(guī)方法制備該材料的周期較長,工藝較為繁瑣。本文利用一步高壓燒結(jié)方法制備了CoSbS1-xSex基固溶體合金,測試并分析了其結(jié)構(gòu)和熱電性能。結(jié)果表明,高壓能夠加快反應(yīng)速率,快速制備出單相CoSbS化合物;加入少量Se能夠同步優(yōu)化三個(gè)熱電參數(shù):即提高Seebeck系數(shù),降低電阻率和熱導(dǎo)率。在673 K時(shí),CoSbS0.8Se0.2具有最大的品質(zhì)因子ZT~0.25,約為母體材料CoSbS的4倍,而且在相同溫度條件下高壓合成樣品的ZT遠(yuǎn)高于傳統(tǒng)方法(固相反應(yīng)結(jié)合放電等離子體燒結(jié))制備CoSbS1-xSex的數(shù)值。這些結(jié)果表明,高壓方法是制備CoSbS基熱電材料的一種有效方法。

    Abstract:

    Paracostibite (CoSbS), as a thermoelectric material, has attracted much attention recently. It has many advantages such as low cost and environment-friendly. However, the thermoelectric performance is limited by the high thermal conductivity. In addition, the preparation of this material need a long-duration heating process and a complicated process by conventional method. In this paper, CoSbS1-xSex based solid solution alloys were facile and rapidly prepared by one-step high pressure method. Their structures and thermoelectric properties were investigated. The results show that high pressure can accelerate the reaction rate and fabricate single-phase CoSbS quickly. Alloying with a small amount of Se can simultaneously optimize three thermoelectric parameters: increasing Seebeck coefficient, reducing resistivity and thermal conductivity. CoSbS0.8Se0.2 has the largest figure of merit ZT~0.25 at 673 K, which is about four times as much as that of the parent material CoSbS. Moreover, the ZT of high-pressure synthesized samples at the same temperature is higher than that of CoSbS1-xSex prepared by the traditional solid-state reaction combined with spark plasma sintering method. These results indicate that high pressure method is an effective method for preparing CoSbS based thermoelectric materials.

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引用本文

朱紅玉,楊曼曼,李洪濤,杜景陽,李尚升,胡美華,胡強(qiáng),杜保立,宿太超.高壓制備CoSbS1-xSex(x=0~0.3)的熱電性能[J].稀有金屬材料與工程,2020,49(4):1422~1426.[Zhu Hongyu, Yang Manman, Li Hongtao, Du Jingyang, Li Shangsheng, Hu Meihua, Hu Qiang, Du Baoli, Su taichao. High Pressure Synthesis and Thermoelectric Performance of CoSbS1-xSex(x=0~0.3)[J]. Rare Metal Materials and Engineering,2020,49(4):1422~1426.]
DOI:10.12442/j. issn.1002-185X.20181308

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  • 收稿日期:2018-12-28
  • 最后修改日期:2019-04-09
  • 錄用日期:2019-04-10
  • 在線發(fā)布日期: 2020-05-07
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