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鈣鈦礦太陽(yáng)能電池穩(wěn)定性的研究進(jìn)展
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1.西安工業(yè)大學(xué);2.西安交通大學(xué)

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Research progress in stability of perovskite solar cells
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    摘要:

    鈣鈦礦太陽(yáng)能電池經(jīng)過(guò)近10年的研究展示出高的光電轉(zhuǎn)換效率(公證PCE達(dá)到23.3%)、低成本、容易制備等優(yōu)勢(shì),具有十分廣闊的商業(yè)化前景。然而,鈣鈦礦太陽(yáng)能電池的穩(wěn)定性問(wèn)題始終沒(méi)有系統(tǒng)性地解決辦法,嚴(yán)重阻礙其進(jìn)一步的發(fā)展。本文回顧了鈣鈦礦太陽(yáng)能電池的發(fā)展歷程,總結(jié)了影響鈣鈦礦太陽(yáng)能電池穩(wěn)定性的幾個(gè)重要因素,包括水汽、氧氣、光照和高溫條件對(duì)鈣鈦礦層的化學(xué)穩(wěn)定性以及電子傳輸層(ETL)、空穴傳輸層(HTL)和制備工藝對(duì)電池穩(wěn)定性的影響,對(duì)穩(wěn)定機(jī)制進(jìn)行了分析,提出了改善穩(wěn)定性的一些方法,并根據(jù)目前的研究成果展望了鈣鈦礦太陽(yáng)能電池的發(fā)展趨勢(shì)。

    Abstract:

    About 10 years of research on perovskite solar cells, it has demonstrated advantages such as higher photoelectric conversion efficiency (notarized PCE of 23.3%), lower cost, simple preparation methods, and has a broad commercial prospects. However, the stability of perovskite solar cells has not been solved, which seriously hinders its further development. This article reviews the development of perovskite solar cells at first. Then, we summarize some important factors that affecting the stability of perovskite solar cells, including water vapor, oxygen, lights, high temperature conditions, electron transport layer (ETL), hole transport layer (HTL) and preparation methods. Meanwhile, we focus on the understanding of the instability mechanism and find some ways to improve the stability of cells. In the end, basing on the current research, we forecasted the development of perovskite solar cells.

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戴中華,謝景龍,劉衛(wèi)國(guó),姚熹.鈣鈦礦太陽(yáng)能電池穩(wěn)定性的研究進(jìn)展[J].稀有金屬材料與工程,2020,49(1):377~384.[Dai Zhonghua, Xie Jinglong, Liu Weiguo, Yao Xi. Research progress in stability of perovskite solar cells[J]. Rare Metal Materials and Engineering,2020,49(1):377~384.]
DOI:10.12442/j. issn.1002-185X.20181185

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  • 收稿日期:2018-11-26
  • 最后修改日期:2018-12-29
  • 錄用日期:2019-01-09
  • 在線發(fā)布日期: 2020-02-16
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