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鈦表面激光熔覆NiCr-Ag復(fù)合涂層結(jié)構(gòu)及空間摩擦學(xué)性能研究
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安徽科技學(xué)院機(jī)械工程學(xué)院

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Microstructure and Space Tribological Properties of Laser Clad NiCr-Ag Composite Coating on Pure Ti Substrate
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College of Mechanical Engineering,Anhui Science and Technology University

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    摘要:

    利用激光熔覆技術(shù)在鈦基材表面制備了NiCr-Ag復(fù)合涂層。用XRD、SEM和HRTEM分析了涂層的組成和組織結(jié)構(gòu),利用空間摩擦學(xué)系統(tǒng)對(duì)復(fù)合涂層在三種模擬空間環(huán)境(高真空、原子氧和紫外輻照)以及大氣環(huán)境下的摩擦磨損性能進(jìn)行了系統(tǒng)的研究。采用SEM和EDS對(duì)磨損后復(fù)合涂層和對(duì)偶鋼球的形貌和元素面分布進(jìn)行了分析,揭示了復(fù)合涂層在模擬空間環(huán)境及大氣環(huán)境下摩擦磨損失效機(jī)理。結(jié)果表明:復(fù)合涂層在大氣環(huán)境條件下的摩擦磨損性能優(yōu)于在三種模擬空間環(huán)境下的摩擦磨損性能;真空下的輻照對(duì)復(fù)合涂層的摩擦磨損性能有顯著的影響,輻照會(huì)增加涂層表面氧化;復(fù)合涂層在高真空、原子氧和紫外輻照模擬空間環(huán)境下的磨損機(jī)理為較嚴(yán)重的粘著磨損、磨粒磨損和塑性變形,在大氣環(huán)境條件下的磨損機(jī)理主要為磨粒磨損。

    Abstract:

    The composite coating NiCr-Ag was successfully prepared by lase clad on substrate of pure Ti in order to enhance space tribological properties of pure Ti, with hard phase NiCr as the reinforcing agent and Ag as the primary lubricating fillers. The composition and microstructure of the fabricated composite coating were investigated by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), and high-resolution transmission electron microscopy (HRTEM). Furthermore, the space tribological properties were systematically evaluated by a ball-on-disc tribometer against AISI-52100 ball counterpart under simulated space environment including atomic oxygen (AO), ultraviolet irradiation (UV), and high vacuum (VC) in comparison with that in atmospheric environment (AR) through the space tribological test system. The results show that the composite coating has better tribological properties in atmospheric environment than those in simulation space environment. Findings indicate that the vacuum (without any moisture or hydrocarbons) and intense radiation in the space environment would induce severe oxidation on the surface of the coating, making the enhancement of the coating weak and the lubrication effect deteriorated. The wear mechanism is abrasive wear under atmospheric environment. Adhesion wear and plastic deformation are the predominant wear mechanism under space environment as peeling pits and transferred Ni, Cr, and Ti could be found on the worn surface and the surface of the counterpart, respectively.

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郭純,陳豐,魏寶麗,張華.鈦表面激光熔覆NiCr-Ag復(fù)合涂層結(jié)構(gòu)及空間摩擦學(xué)性能研究[J].稀有金屬材料與工程,2020,49(4):1191~1199.[Guo Chun, Chen Feng, Wei Baoli, Zhang Hua. Microstructure and Space Tribological Properties of Laser Clad NiCr-Ag Composite Coating on Pure Ti Substrate[J]. Rare Metal Materials and Engineering,2020,49(4):1191~1199.]
DOI:10.12442/j. issn.1002-185X.20181165

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  • 收稿日期:2018-11-20
  • 最后修改日期:2018-12-10
  • 錄用日期:2019-01-09
  • 在線發(fā)布日期: 2020-05-07
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