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原位自生SiC納米線摻雜SiOC陶瓷粉體的制備與介電性能
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1.西北工業(yè)大學(xué)超高溫結(jié)構(gòu)復(fù)合材料重點(diǎn)實(shí)驗(yàn)室;2.西北工業(yè)大學(xué)

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國家自然科學(xué)基金項(xiàng)目(51602258, 51432008, 51502242, 51725205, 51332004), 陜西省自然科學(xué)基礎(chǔ)研究計(jì)劃(No. 2017JM5094)


Silicon oxycarbide Powders doped with in situ grown SiC Nanowires: Synthesis and dielectric property
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Affiliation:

1.Science and Technology on Thermostructural Composite Materials Laboratory,Northwestern Polytechnical University;2.Northwestern Polytechnical University

Fund Project:

National Natural Science Foundation of China (51602258, 51432008, 51502242, 51725205, and 51332004), Natural Science Basic Research Plan in Shaanxi (No. 2017JM5094)

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    摘要:

    以二茂鐵為催化劑,催化裂解陶瓷聚合物先驅(qū)體制備了原位自生SiC納米線摻雜的SiOC陶瓷粉體。SiC納米線為堆垛方向?yàn)?amp;lt;111>的β相單晶體,直徑為10-100nm,長度可達(dá)數(shù)微米,均勻分布在SiOC粉體中?;赟iC納米線微觀結(jié)構(gòu)分析,探討了納米線的生長機(jī)制。研究了復(fù)合陶瓷粉體的介電性能,結(jié)果發(fā)現(xiàn),SiC納米線含量可調(diào)控復(fù)合粉體的電性能,較高含量納米線可賦予復(fù)合粉體較高的介電實(shí)部與虛部。

    Abstract:

    The amorphous silicon oxycarbide powders containing in situ-grown single-crystal silicon carbide nanowires were fabricated via the pyrolysis of a polymeric precursor with ferrocene as the catalyst. The nanowires, with lengths of several micrometers and diameters of 10-100 nm, were composed of single-crystal β-SiC along the <111> growth direction and uniformly dispersed in the composite powders. The growth mechanism of silicon carbide nanowires was explored by analyzing the microstructure of the silicon carbide nanowires. The dielectric properties of the composite ceramic powders were studied, which demonstrates that silicon carbide nanowires can be used to adjust the electrical of the composite and a high nanowire content can result in a large real and imaginary part of permittivity.

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葉昉,段文艷,莫然,殷小瑋,張立同,成來飛.原位自生SiC納米線摻雜SiOC陶瓷粉體的制備與介電性能[J].稀有金屬材料與工程,2019,48(1):39~43.[Fang Ye, Wenyan Duan, Ran Mo, Xiaowei Yin, Litong Zhang, Laifei Cheng. Silicon oxycarbide Powders doped with in situ grown SiC Nanowires: Synthesis and dielectric property[J]. Rare Metal Materials and Engineering,2019,48(1):39~43.]
DOI:10.12442/j. issn.1002-185X.20180798

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  • 收稿日期:2018-07-24
  • 最后修改日期:2018-09-27
  • 錄用日期:2018-10-08
  • 在線發(fā)布日期: 2019-02-18
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