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電極感應(yīng)熔煉氣霧化制備Ti-6Al-4V合金粉末的性能及其表征
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作者單位:

1.國家金屬材料近凈成形工程技術(shù)研究中心;2.佛山市歲之博新材料科技有限公司

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中圖分類號:

TG144

基金項目:

國家自然科學(xué)基金重大儀器專項(516227805),廣東省自然科學(xué)基金團隊項目(2015A030312003),廣東省科技攻關(guān)項目(2014B010129003、2016B090931006、2017B090901025),廣州市科技攻關(guān)項目(201604016049)


Properties and Characterization of Fine Ti-6Al-4V Alloy Powders Prepared by Electrode Induction melting Gas Atomization (EIGA) Technique
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National Engineering Research Center of Near-Net-Shape Forming for Metallic Material

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    摘要:

    采用國產(chǎn)自行研制的無坩堝電極感應(yīng)熔煉氣體霧化(EIGA)設(shè)備制備Ti-6Al-4V合金粉末,實驗使用環(huán)孔型和環(huán)縫型兩種氣霧化噴嘴,改變霧化壓力和熔煉功率,設(shè)計四組工藝參數(shù),研究霧化工藝對粉末性能的影響規(guī)律。根據(jù)激光選區(qū)熔化(SLM)對粉末的要求,將篩分得到的粒徑小于53 μm的粉末進行表征,采用MASTERSIZE 2000激光粒度分析儀分析不同霧化工藝制備粉末的粒度分布,采用歐奇奧500NanoXY+HR型粒度粒形分析儀對粉末的粒形進行量化表征分析。結(jié)果表明,采用環(huán)縫型噴嘴、5 MPa的霧化壓力和25 kW的熔煉功率的工藝參數(shù)組合制備的粉末效果最佳,得到的粉末粒徑較小且分布集中,粉末粒度呈近似正態(tài)分布,D10、D50和D90分別為19.4 μm、31.9 μm和51.5 μm;粉末的球形度較高,粉末圓度的平均值為90.6%,歐奇奧鈍度的平均值為92.7%,超過80%的粉末贅生物指數(shù)為0,衛(wèi)星粉較少。通過XRD、SEM、EDS能譜和氧氮儀等手段對粉末進一步分析,發(fā)現(xiàn)粉末內(nèi)部組織為不同取向的針狀α′馬氏體,空心粉含量較少,粉末成分無損耗且氧含量較低。對該粉末進行SLM成形,成形件致密度達到99.02%,表面粗糙度為4.98 μm,顯微硬度為352.5 HV0.5。

    Abstract:

    Ti-6Al-4V alloy powders were prepared by a self-developed electrode induction melting gas atomization (EIGA) equipment. Two kinds of gas atomizing nozzles, ring-hole type and ring-slit type, were used in the experiment. Different atomization pressure and power input were used. Four sets of processing parameters were designed and their effect on the powder properties was studied. The powder were sieved by 270 standard mesh (powder particle size ≤53μm) and analyst the size distribution by using MASTERSIZE 2000 Laser Particle Size Analyzer. The powder particle shape was quantified with Occhio 500NanoXY+HR Particle Size and Shape Analyzer. Results showed that optimal results were achieved with good sphericity by the combination of ring-slit nozzle with atomization pressure of 5 MPa and smelting power of 25 kW. A normal distribution of powder size was attained and the D10, D50 and D90 were 19.4μm, 31.9μm and 51.5μm, respectively. The mean Circularity and Occhio bluntness were 90.6% and 92.7%, respectively. It was found that more than 80% of powders have Occhio outgrow of 0. Further analysis of the powder by XRD, SEM, EDS and oxygen and nitrogen analyzer were carried out. The microstructure of the powder was acicular α′ martensite with random orientations. The amount of hollow powder is extremely small. The powder composition is practically same as the ingot with a low oxygen content, which satisfies the requirements of the SLM process. The Ti-6Al-4V powder achieved by optimal process was used for Selective Laser Melting and the relative density, surface roughness and microhardness are 99.02% and 4.89 μm, and 352.5 HV0.5 respectively.

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引用本文

黃傳收,柳中強,吳苑標,溫利平,陳進,肖志瑜.電極感應(yīng)熔煉氣霧化制備Ti-6Al-4V合金粉末的性能及其表征[J].稀有金屬材料與工程,2019,48(10):3302~3308.[Huang Chuan-shou, Liu Zhong-qiang, Wu Yuan-biao, Wen Li-ping, Chen Jin, Xiao Zhi-yu. Properties and Characterization of Fine Ti-6Al-4V Alloy Powders Prepared by Electrode Induction melting Gas Atomization (EIGA) Technique[J]. Rare Metal Materials and Engineering,2019,48(10):3302~3308.]
DOI:10.12442/j. issn.1002-185X.20180592

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  • 收稿日期:2018-06-05
  • 最后修改日期:2018-07-17
  • 錄用日期:2018-07-27
  • 在線發(fā)布日期: 2019-11-01
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