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基于NaCl Beads制備的泡沫Al孔結(jié)構(gòu)控制與表征
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蘭州理工大學(xué) 甘肅省有色金屬先進(jìn)加工與再利用國(guó)家重點(diǎn)實(shí)驗(yàn)室

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TG146

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國(guó)家自然科學(xué)基金資助(51461029);甘肅省科技重大專項(xiàng)計(jì)劃項(xiàng)目(1602GKDD012)


Structure and Control Characterization of Al Foam Pores Prepared by NaCl Beads
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State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology

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    摘要:

    以淀粉、蒸餾水、NaCl粉末為原料,混合制成膠狀鹽團(tuán)后70℃油浴加熱,同時(shí)在機(jī)械攪拌切削的作用下得到球形度較高的NaCl小球,然后經(jīng)高溫?zé)Y(jié)獲得粒徑分布主要在0.4-2.4mm,表面分布有少量微孔(孔徑約10-20μm)且純凈度很高的NaCl小球。選用0.6-1.0mm的鹽球作為造孔劑,利用Autotap震動(dòng)將鋁粉填入“鹽床”縫隙,再經(jīng)200MPa冷壓成型后獲得生坯,然后在蒸餾水中浸泡將鹽球溶解去除,最后在460℃下燒結(jié)2h得到結(jié)構(gòu)可控且工藝重現(xiàn)性很高的三維連通開孔性泡沫鋁,其相對(duì)密度與孔隙率分別為0.217和78.3%。泡沫鋁胞洞之間的連通窗口數(shù)量平均在4-6個(gè),窗口尺寸約在120-200μm之間;壓縮載荷-位移曲線表明泡沫鋁在壓縮變形過程中經(jīng)歷了彈性變形階段-坪應(yīng)力區(qū)-應(yīng)力陡增階段,表現(xiàn)出典型的泡沫金屬壓縮力學(xué)性能特點(diǎn),其最大抗壓強(qiáng)度與楊氏模量分別是2.42MPa和0.38GPa。

    Abstract:

    NaCl beads were prepared using starch, distilled water and NaCl powders as raw materials.The raw constituents were mixed to form a colloidal salt paste and then thermal treated in 70°C oil under vigorous stirring, high spherical NaCl beads were obtained under the cutting action of the blender. Afterwards, the “fried” NaCl beads with a particle size distribution of 0.4-2.4mm were calcined and sintered at 740°C, and thus the high purity NaCl beads with small amount of micro-pore (pores size about 10-20μm) on the surface were obtained. The 0.6-1.0mm salt beads were selected to form a “salts bed” in a steel die and the aluminum powder was filled into “salt bed” gap via a tapping method by the Autotap instrument.The tapped mixture was cold pressed under 200MPa to obtain the green compact parts. Then the salts were dissolved and removed in distilled water and three-dimensional open-cell green Al foam with controllable structure and highly reproducibility was derived. After sintering at 460 °C for 2 h, the final Al foam was obtained and its relative density and porosity were 0.217 and 78.3%. The number of connectivity windows between cellular aluminum cells is 4-6 on average, and the window size is about 120-200 μm. The compressive load-displacement curve shows that the aluminum foam undergoes an elastic deformation stage - the plateau stress area - the stress steep increase stage, The curvemanifest typical foam metal compression mechanical properties, and its compressive strength and Young''s modulus are 2.42 MPa and 0.38 GPa.

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賈建剛,井勇智.基于NaCl Beads制備的泡沫Al孔結(jié)構(gòu)控制與表征[J].稀有金屬材料與工程,2019,48(10):3275~3281.[jia jian gang, jing yong zhi. Structure and Control Characterization of Al Foam Pores Prepared by NaCl Beads[J]. Rare Metal Materials and Engineering,2019,48(10):3275~3281.]
DOI:10.12442/j. issn.1002-185X.20180558

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  • 收稿日期:2018-05-29
  • 最后修改日期:2018-06-22
  • 錄用日期:2018-06-27
  • 在線發(fā)布日期: 2019-11-01
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