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高壓扭轉(zhuǎn)對Al-Zn-Mg-Cu-Zr合金抗應力腐蝕性能影響
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合肥工業(yè)大學

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TG311

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國家自然科學基金項目(面上項目,重點項目,重大項目)


Effect of high pressure torsion on stress corrosion resistance of Al-Zn-Mg-Cu-Zr aluminum alloy
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Hefei University of Technology

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    摘要:

    在400 ℃下對鑄態(tài)Al-Zn-Mg-Cu-Zr合金進行壓強為1GPa的高壓扭轉(zhuǎn)和熱處理實驗,并利用金相顯微鏡、電化學工作站、慢應變速率拉伸機測試初始及變形試樣的顯微組織、電化學腐蝕性能及抗應力腐蝕性能。結(jié)果表明,高壓扭轉(zhuǎn)通過調(diào)控晶粒和第二相的尺寸與分布,可以同時提升7系鋁合金的抗拉強度和抗應力腐蝕性能。鑄態(tài)合金由于晶界處團聚的粗大第二相持續(xù)腐蝕,導致明顯的晶間腐蝕及較差的抗應力腐蝕性能。0.5圈變形后第二相破碎及含量減少導致試樣腐蝕敏感性降低,同時晶粒細化能減小面滑移而增大均值滑移模式,使HPT變形后試樣的抗應力腐蝕性能顯著提升。2圈變形后試樣為尺寸更加細小的均勻細晶組織,其均值滑移模式相比于0.5圈變形試樣進一步增強,但在劇烈點蝕與應力集中的共同作用下,抗應力腐蝕性能略有降低。

    Abstract:

    High pressure torsion (HPT) experiment followed with heat treatment were carried out on as-received Al-Zn-Mg-Cu-Zr alloy at 400 ℃ under the pressure of 1 GPa. Optical microscope, electrochemical workstation and slow strain rate tensile machine were used for microstructure observation, electrochemical corrosion and stress corrosion resistance test for the as-received and HPT processed samples respectively. The results show that HPT processing can improve the tensile strength and stress corrosion resistance by modifying the size and distribution of grains and second phases. The second phases agglomerated at the grain boundary corrode continuously, which leads to obvious intergranular corrosion and weak stress corrosion resistance of the as-received alloy. After 0.5 turn of HPT processing, the fragmentation and content reduction of second phase lead to the decrease of corrosion sensitivity, at the same time, the planar slip reduces and homogeneous slip mode increases due to grain refinement, which synthetically results in a significant improvement of the stress corrosion resistance. The HPT processed sample with 2 turns has finer grains with uniform distribution, which leads to the further increases of homogeneous slip mode compared with 0.5 turn, but under the interaction of intense pitting and stress concentration, the resistance to stress corrosion slightly decreases.

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李萍,吳廣善,魏學峰,王薄笑天,嚴思梁,薛克敏.高壓扭轉(zhuǎn)對Al-Zn-Mg-Cu-Zr合金抗應力腐蝕性能影響[J].稀有金屬材料與工程,2019,48(9):2981~2986.[Li Ping, Wu Guangshan, Wei Xuefeng, Wang Boxiaotain, Yan Siliang, Xue Kemin. Effect of high pressure torsion on stress corrosion resistance of Al-Zn-Mg-Cu-Zr aluminum alloy[J]. Rare Metal Materials and Engineering,2019,48(9):2981~2986.]
DOI:10.12442/j. issn.1002-185X.20180537

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  • 收稿日期:2018-05-24
  • 最后修改日期:2018-06-23
  • 錄用日期:2018-07-27
  • 在線發(fā)布日期: 2019-10-09
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