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元素硫?qū)2S + CO2飽和氯溶液中合金G3腐蝕的影響
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1.西南石油大學(xué)材料科學(xué)與工程學(xué)院;2.西南石油大學(xué)油氣藏地質(zhì)及開發(fā)工程國(guó)家重點(diǎn)實(shí)驗(yàn)室

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國(guó)家自然科學(xué)基金項(xiàng)目(面上項(xiàng)目,重點(diǎn)項(xiàng)目,重大項(xiàng)目)


The influence of elemental sulfur on the corrosion of Alloy G3 in H2S+CO2 saturated chloride solution
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School of Materials Science and Engineering, Southwest Petroleum University

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    摘要:

    本研究中利用電化學(xué)顯微鏡(SECM)、掃描電子顯微鏡(SEM)和電化學(xué)阻抗譜(EIS)研究了鎳基合金G3在室溫(25℃)和高溫(90℃)、含H2S、CO2,Cl-介質(zhì)環(huán)境中各種硫狀態(tài)下的腐蝕行為。結(jié)果表明,隨溫度升高,腐蝕變得更加嚴(yán)重,鎳基合金G3表面出現(xiàn)輕微的點(diǎn)蝕;陽(yáng)極極化曲線在室溫下具有鈍化區(qū),而在90℃的溫度下出現(xiàn)活性溶解區(qū),鈍化現(xiàn)象消失。物相分析表明在鎳基合金G3上形成鈍化膜主要由Ni、Cr及Fe的氧化物組成,由于S2-侵入薄膜導(dǎo)致鈍化膜溶解,腐蝕產(chǎn)物由NiS、FeS2組成。G3合金在含硫環(huán)境中的耐腐蝕性減弱,相比較沉積硫、析出硫,硫懸浮狀態(tài)下鎳基合金G3表面鈍化膜最致密,腐蝕最輕微。研究表明硫是強(qiáng)催化劑,其存在導(dǎo)致嚴(yán)重的局部腐蝕,元素硫的狀態(tài)是影響腐蝕產(chǎn)物膜的致密性和生長(zhǎng)速率的關(guān)鍵因素,也是影響合金腐蝕速率的關(guān)鍵因素。

    Abstract:

    The corrosive behavior of the nickel-based alloy G3 at room temperature (25℃) and high temperature (90℃) in a complex medium environment containing H2S, CO2, Cl- with various states of elemental sulfur was studied by using electrochemical microscope (SECM), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) in this paper, and the influence of elemental sulfur was analyzed. The results show that the corrosion becomes more serious with increasing temperature and slight pitting occurs on the surface of the nickel-based alloy G3. The anode polarization curve has a passivation region at room temperature, but the active dissolution appears and passivation disappears at a temperature of 90℃. The phases were analyzed that the passivation film formed on the surface of the nickel-based alloy G3 is mainly composed of oxides of Ni, Cr and Fe. The passivation film is dissolved due to the intrusion of S2-, and the corrosion products were composed of NiS and FeS2. The corrosion resistance of G3 alloy is weakened in the sulfur-contained environment, and the suspended sulfur has the most dense passivation film and the least corrosion rate compared with the deposition of sulfur and the precipitation of sulfur. Studies have shown that sulfur is a strong catalyst, and its existence leads to severe local corrosion. The state of elemental sulfur is a key factor affecting the compactness and growth rate of corrosion product membranes and the corrosion rate of alloys.

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范舟,王子瑜,劉建儀,黃泰愚,趙星.元素硫?qū)2S + CO2飽和氯溶液中合金G3腐蝕的影響[J].稀有金屬材料與工程,2019,48(10):3167~3174.[fanzhou, wangziyu, liujianyi, huangtaiyu, zhaoxing. The influence of elemental sulfur on the corrosion of Alloy G3 in H2S+CO2 saturated chloride solution[J]. Rare Metal Materials and Engineering,2019,48(10):3167~3174.]
DOI:10.12442/j. issn.1002-185X.20180462

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  • 收稿日期:2018-05-07
  • 最后修改日期:2018-11-05
  • 錄用日期:2018-11-08
  • 在線發(fā)布日期: 2019-11-01
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