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TC21合金α+β→β相變時(shí)膨脹與合金元素 配分行為
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貴州大學(xué)材料與冶金學(xué)院

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中圖分類號(hào):

TG146.4

基金項(xiàng)目:

貴州省科學(xué)技術(shù)基金項(xiàng)目(20171023);貴州省教育廳青年科技人才成長(zhǎng)項(xiàng)目(2016122);貴州大學(xué)引進(jìn)人才科研項(xiàng)目(201633);國(guó)家自然科學(xué)基金項(xiàng)目(51401058);貴州省創(chuàng)新人才團(tuán)隊(duì)


Expansion and Partitioning Behavior of Alloy Elements In α+β→β Phase Transformation of TC21 Alloy
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School of materials and metallurgy.Guizhou university.

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    摘要:

    采用膨脹法、OM、SEM和TEM研究了TC21鈦合金在連續(xù)加熱過(guò)程中α+β→β時(shí)線膨脹效應(yīng)和合金元素的配分行為。結(jié)果表明: TC21合金在連續(xù)加熱過(guò)程中α+β→β時(shí)長(zhǎng)度的變化,一方面來(lái)源于密排六方α相向體心立方的β相的轉(zhuǎn)變影響,另一方面合金α相不斷溶解過(guò)程中伴隨著α相穩(wěn)定元素和β穩(wěn)定元素在兩相中的配分,也會(huì)導(dǎo)致試樣的軸向長(zhǎng)度變化。同時(shí)發(fā)現(xiàn)在α+β→β過(guò)程中,α相中Al元素隨著α相不斷溶解濃度逐漸下降,而在β相中濃度逐漸升高,由于合金元素Al含量增加對(duì)α相體積影響不大,但使β相的體積縮小,這是TC21合金長(zhǎng)度收縮的主要原因。然而合金元素Mo、Cr、Nb在α→α+β轉(zhuǎn)變過(guò)程中又向α相中擴(kuò)散,在相互擴(kuò)散過(guò)程中還在α/β界面上出現(xiàn)成分不平衡的現(xiàn)象。

    Abstract:

    The expansion behavior and partitioning behavior of alloying elements in α+β→β phase transformation of TC21 titanium alloy during continuous heating were carried out by combining dilatometric method, optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that the change in the length of the TC21 alloy during the continuous heating process results from the transformation of α phase with hexagonal close-packed to β phase with body-centered cubic and macro volume variation which originates from redistribution of α-stabilizers and β-stabilizers in the alloy during the continuous dissolution of α phase when the temperature is over β transformation temperature. It is found that the content of Al element increases in the α phase with the dissolution of α phase, but it decreases in the β phase. Additionally, the increasing content of Al element leads to decrease in volume of β phase, which is also main reason for shrinking of the alloy during α+β→β phase transformation. However, Mo, Cr and Nb element diffuse to the α phase during α→α+β phase transformation, so that the composition imbalance was found at the α/β interface.

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引用本文

包國(guó)濤,雷 旻,萬(wàn)明攀,黃朝文. TC21合金α+β→β相變時(shí)膨脹與合金元素 配分行為[J].稀有金屬材料與工程,2019,48(10):3325~3330.[baoguotao, leimin, wanmingpan, huangchaowen. Expansion and Partitioning Behavior of Alloy Elements In α+β→β Phase Transformation of TC21 Alloy[J]. Rare Metal Materials and Engineering,2019,48(10):3325~3330.]
DOI:10.12442/j. issn.1002-185X.20180447

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  • 收稿日期:2018-05-03
  • 最后修改日期:2018-08-17
  • 錄用日期:2018-08-31
  • 在線發(fā)布日期: 2019-11-01
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