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包埋法Co-Cr-Y改性高溫合金GH586滲鋁涂層高溫氧化行為
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Nantong Sipping College

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High temperature oxidation behavior of Co-Cr-Y-modified Aluminide Coatings on Ni-based superalloy by pack cementation process
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Mechanical and Electrical Department,Nantong Shipping College,Nantong

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    摘要:

    通過粉末包埋法運用Co-Cr-Y對高溫合金GH586滲鋁涂層進行改性,并進行了高溫氧化行為的研究。研究結果表明:經Co-Cr-Y改性后的滲鋁涂層在1000 °C氧化100h后,其平均增重為0.36毫克/平方厘米,遠遠低于基體的增重量。經X射線衍射分析,涂層的主要物相為NiAl,在1000 °C氧化過程中生成了連續(xù)而致密的氧化膜,主要包含 Al2O3, Cr2O3和 CoCr2O4。通過掃描電鏡觀察涂層表面和截面的形貌,可以涂層比基體展現出了更為優(yōu)秀的氧化性能。另外發(fā)現,氧化過程中的富Cr(W)在晶界上聚集,有利于為涂層生成連續(xù)而致密的氧化膜不斷提供Cr元素,從而提高涂層高溫氧化性能。

    Abstract:

    In this work the microstructures and high temperature oxidation behaviors of Co-Cr-Y modified pack aluminide coatings on Ni-based superalloy GH586 were investigated. The results indicated that the specific Co-Cr-Y-modified aluminide coating had a mass gain of only 0.36 mg/cm2 after oxidation at 1000 °C for 100 h, it was much less than that of the substrate at 1000 °C. From the X ray diffraction the phases of the coatings were mainly AlNi, and after oxidation for 100h at 1000 °C the denser oxidation scale was composed of Al2O3, Cr2O3, and CoCr2O4. The surface and cross sectional morphologies were characterized by scanning electron microscope (SEM). The coating exhibited the better high temperature oxidation resistance, compared to the oxidation film of GH586 without coating. Moreover, the growing Cr (w) rich phase was gradually gathered in the grain boundaries during the oxidation, it is beneficial to provide more Cr element for the dense oxidation film, which is mainly attributed to the excellent high temperature oxidation resistance.

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曹將棟.包埋法Co-Cr-Y改性高溫合金GH586滲鋁涂層高溫氧化行為[J].稀有金屬材料與工程,2018,47(12):3616~3623.[Cao Jiangdong. High temperature oxidation behavior of Co-Cr-Y-modified Aluminide Coatings on Ni-based superalloy by pack cementation process[J]. Rare Metal Materials and Engineering,2018,47(12):3616~3623.]
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  • 收稿日期:2018-03-31
  • 最后修改日期:2018-05-19
  • 錄用日期:2018-05-21
  • 在線發(fā)布日期: 2019-01-04
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