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ZrC增強細晶鎢材料的高溫性能和高熱負荷沖擊性能研究
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中南大學 粉末冶金國家重點實驗室

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:國家自然科學基金資助(項目號51474242和51404308) 和國家科技部重大專項(項目號2014GB115000))


High Temperature Properties and High Heat Flux Shock Behavior of Fine Grain Tungsten Reinforced by ZrC Particles
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China State Key Laboratory for Powder Metallurgy,Central South University,Changsha,410083

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    摘要:

    采用常壓氫氣燒結制備了W-ZrC材料,研究了添加ZrC對材料室溫和高溫力學性能與組織的影響,并對高熱負荷沖擊下的損傷行為進行了研究。結果表明,添加ZrC有利于鎢材料的致密化和晶粒細化,提高了燒結態(tài)鎢材料的強韌性:其中W-3wt%ZrC相對密度和室溫拉伸強度分別達到99.7%和472MPa,400℃至1000℃的拉伸強度在420MPa左右,應變由室溫的3.4%增加至1000℃時的11%。高熱負荷沖擊結果表明高強度能提高材料抗高熱負荷沖擊能力,W-3wt%ZrC材料在200 MW/m2 (5 ms)以下的高熱負荷沖擊表面基本無裂紋,在300-400MW/m2時出現(xiàn)的主裂紋網(wǎng)格間距明顯較W-0.7wt%ZrC小。隨高熱負荷沖擊能量增加,裂紋大致沿縱向向基體內(nèi)部逐漸擴展。裂紋擴展遇到第二相粒子時,部分穿過第二相粒子,部分終止于第二相粒子。裂紋穿過第二相粒子時,裂紋與第二相粒子發(fā)生了交互作用,裂紋擴展方向發(fā)生改變。

    Abstract:

    W-ZrC materials were prepared by ordinary consolidation sintering. The effects of ZrC addition on the mechanical properties and microstructure of the materials at room temperature and high temperature were studied, and the damage behavior under high heat flux shock was studied. The results show that ZrC is beneficial to densification and grain refinement, and improve the strength and toughness of W materials. The relative density and tensile strength of W-3wt%ZrC can reach 99.7% and 472MPa. The relative density and room temperature tensile strength of W-3wt%ZrC were 99.7% and 472MPa, respectively, and the tensile strength at 400 to 1000 C did not decrease at 420MPa, but the strain increased from 3.4% at room temperature to 11% at 1000 C. High heat flux shock show that high strength can improve the impact resistance of materials against high heat load. The surface of W-3wt%ZrC material has no cracks load under high heat flux shock of 200 MW/m2 (5 ms). The main crack spacing of W-3ZrC is smaller than W-0.7wt%ZrC at 300-400MW/m2. With the increase of the high heat load energy, the cracks gradually expand along the longitudinal direction. Microstructure shows that ZrC can consume the crack propagation energy and hinder crack propagation.

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李鵬飛,范景蓮,章曼,韓勇,孫志雨,呂永齊,田家敏. ZrC增強細晶鎢材料的高溫性能和高熱負荷沖擊性能研究[J].稀有金屬材料與工程,2019,48(2):517~523.[Li Pengfei, Fan Jinglian, Zhang Man, Han Yong, Sun Zhiyu, Lv Yongqi, Tian Jiamin. High Temperature Properties and High Heat Flux Shock Behavior of Fine Grain Tungsten Reinforced by ZrC Particles[J]. Rare Metal Materials and Engineering,2019,48(2):517~523.]
DOI:10.12442/j. issn.1002-185X.20180167

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  • 收稿日期:2018-02-25
  • 最后修改日期:2018-04-10
  • 錄用日期:2018-04-26
  • 在線發(fā)布日期: 2019-03-15
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