3+濃度為30g/L,電流密度為130 A/cm2,連續(xù)電解時(shí)間為1h,NaCl濃度80g/L,極距5cm,硫脲濃度0.3g/L,明膠濃度0.5g/L,pH=2.5,聚乙烯吡咯烷酮用量為0.2g/L。在此工藝條件下電解,極距的大小,基本不影響粉體的純度,但對(duì)粉體的粒度影響較大;NaCl濃度對(duì)粉體純度影響最大;電解液溫度越高,所得粉體粒度變大,粉體純度降低;電解液的pH既影響粉體的純度,又影響粉體的粒度;添加劑硫脲對(duì)粉體的枝晶生長(zhǎng)有抑制作用。在此工藝參數(shù)下電解1h,可得到粒度小于100μm的銦微粉,其中粒度小于30μm的占75%,粉體純度為99.98%,平均電流效率達(dá)70.10%。"/>

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電解工藝參數(shù)對(duì)銦微粉純度和粒度的影響(II)
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1.青海大學(xué) 機(jī)械工程學(xué)院 青海省新型輕合金重點(diǎn)實(shí)驗(yàn)室;2.東北大學(xué) 冶金學(xué)院 多金屬共生礦生態(tài)化冶金教育部重點(diǎn)實(shí)驗(yàn)室

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青海省“高端創(chuàng)新人才千人計(jì)劃”資助項(xiàng)目


Effect of Electrolytic Process Parameters on the Purity andParticle Size of Indium Powder (II)
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1.Key Laboratory of Qinghai Province for Light Alloy,School of Mechanical Engineering,Qinghai University;2.Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education,School of Metallurgy,Northeastern University

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    研究了電解工藝制備銦微粉時(shí),電解溫度、極距、導(dǎo)電鹽濃度、電解液pH、添加劑種類(lèi)對(duì)粉體純度和粒度的影響。結(jié)果表明:電解最佳工藝參數(shù)為In3+濃度為30g/L,電流密度為130 A/cm2,連續(xù)電解時(shí)間為1h,NaCl濃度80g/L,極距5cm,硫脲濃度0.3g/L,明膠濃度0.5g/L,pH=2.5,聚乙烯吡咯烷酮用量為0.2g/L。在此工藝條件下電解,極距的大小,基本不影響粉體的純度,但對(duì)粉體的粒度影響較大;NaCl濃度對(duì)粉體純度影響最大;電解液溫度越高,所得粉體粒度變大,粉體純度降低;電解液的pH既影響粉體的純度,又影響粉體的粒度;添加劑硫脲對(duì)粉體的枝晶生長(zhǎng)有抑制作用。在此工藝參數(shù)下電解1h,可得到粒度小于100μm的銦微粉,其中粒度小于30μm的占75%,粉體純度為99.98%,平均電流效率達(dá)70.10%。

    Abstract:

    :The effect of temperature, the distance of electrodes, conductive salt concentration, pH values and kinds of additives on the purity and size of indium powder by electrolysis process was studied. The results show thatThe optimum process parameters for electrolysis are obtained. (The optimum process parameters for electrolysis as follows: The concentration of In3+ is 30g/L, the current density is 130 A/cm2, continuous electrolysis time is 1 hour, the concentration of NaCl is 80g/L, the distance of electrodes is 5cm, thiourea concentration is 0.3g/L, gelatin concentration is 0.5g/L, pH=2.5 and polyvinylpyrrolidone is 0.2g/L). Under these conditions, the distance of electrodees does not affect the purity of the powder, but affect theparticle size of the powder. The concentration of NaCl has the greatest influence on the purity of the powder.The higher temperature of the electrolyte, the particle size becomes larger and the purity of the powder decreases. The additive of thiourea restraining dendrite growth of the powder. Electrolysis 1 hour under the optimum process parameters, indium powder with a grain size of less than 100μm is obtained. The particle size less than 30μm accounted for 75%, the purity of the powder is 99.98%, and the average current efficiency is 70.10%.

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王曉民,曹海蓮,南輝,王志新,喇學(xué)偉,張廷安.電解工藝參數(shù)對(duì)銦微粉純度和粒度的影響(II)[J].稀有金屬材料與工程,2019,48(6):2038~2043.[Xiao-min Wang, Hai-lian Cao, Hui Nan, Zhi-xin Wang, Xue-wei La, Ting-an Zhang. Effect of Electrolytic Process Parameters on the Purity andParticle Size of Indium Powder (II)[J]. Rare Metal Materials and Engineering,2019,48(6):2038~2043.]
DOI:10.12442/j. issn.1002-185X.20171200

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  • 收稿日期:2017-12-26
  • 最后修改日期:2018-01-17
  • 錄用日期:2018-08-09
  • 在線發(fā)布日期: 2019-07-30
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