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W-Ni-Cu 和W-Ni-Fe合金的腐蝕性能
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曼徹斯特大學(xué),曼徹斯特大學(xué),曼徹斯特大學(xué)

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Corrosion Performance of W-Ni-Cu and W-Ni-Fe Alloys
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University of Manchester,,

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    摘要:

    高比重鎢合金是一種具有高密度,高機(jī)械強(qiáng)度和良好的耐腐蝕性等特性的復(fù)合材料,并廣泛應(yīng)用于工業(yè)和軍事中。本文采用沉浸實(shí)驗(yàn)和電化學(xué)實(shí)驗(yàn)對(duì)兩種鎢合金(90%W-6%Ni-4%Cu和95%W-3.5%Ni-1.5%Fe)的腐蝕性能進(jìn)行了研究。結(jié)果的表明,當(dāng)W-Ni-Cu合金發(fā)生電偶腐蝕時(shí),W相首先遭到腐蝕,而在W-Ni-Fe合金中,粘結(jié)相會(huì)先發(fā)生腐蝕。電動(dòng)位極化測(cè)量結(jié)果表明pH值對(duì)高比重合金鎢合金腐蝕速率有顯著影響,與酸性環(huán)境相比較,合金在中性溶液中得到較低的腐蝕速率。根據(jù)SEM和EDX的結(jié)果分析了合金成分的溶解以及腐蝕產(chǎn)物的生成等腐蝕機(jī)理。

    Abstract:

    Tungsten heavy alloys (WHAs) achieve a special combination of properties, such as high density, high mechanical strength and good corrosion resistance in the industrial and military applications. In this study, the corrosion performance of two WHAs, 90%W-6%Ni-4%Cu and 95%W-3.5%Ni-1.5%Fe has been investigated by immersion test and electrochemical test. The AFM results indicated the attack would be on the W phase in W-Ni-Cu alloy when it generated galvanic corrosion, W-Ni-Fe alloy revealed opposite result. Potentiodynamic polarization measurement showed pH value is an important factor in corrosion rate. The two types alloys showed relatively lower corrosion rates in DI water, as compared to 0.6MHCl solution. The corrosion mechanism was involved in the release of the metallic components and generation of corrosion products in term of SEM and EDX.

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李鷺,Zhu Liu,劉玉項(xiàng). W-Ni-Cu 和W-Ni-Fe合金的腐蝕性能[J].稀有金屬材料與工程,2018,47(6):1708~1715.[li lu, zhu liu, liu yu xiang. Corrosion Performance of W-Ni-Cu and W-Ni-Fe Alloys[J]. Rare Metal Materials and Engineering,2018,47(6):1708~1715.]
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  • 收稿日期:2017-12-22
  • 最后修改日期:2018-02-02
  • 錄用日期:2018-03-12
  • 在線發(fā)布日期: 2018-09-06
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