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氧含量對燒結釹鐵硼磁體Dy晶界擴散的影響研究
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1.鋼鐵研究總院;2.安泰科技股份有限公司

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安泰科技股份有限公司技術創(chuàng)新項目資助(項目號2012JA01GGN)


Influence of Oxygen content on Dy grain boundary diffusion in Nd-Fe-B sintered magnets
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1.Central Iron and Steel Research Institute;2.Advanced Technology and Materials Co., Ltd.;3.Advanced Technology and Materials co,Ltd

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    摘要:

    本文主要研究了燒結釹鐵硼磁體中氧含量變化對Dy晶界擴散后的Dy含量及矯頑力增加量的影響。選取多種高、低氧磁體進行Dy擴散處理后比較發(fā)現(xiàn),低氧磁體的Dy擴散量和矯頑力提高量均明顯高于高氧磁體。對9個0wt.%Dy的不同氧含量樣品進行擴散再次確認,氧含量減少有利于Dy擴散量、矯頑力的提高。各樣品成分梯度結果顯示,低氧磁體的Dy擴散量由表及里全面高于高氧磁體,內外濃度梯度也小于后者。電子探針表征結果表明,低氧磁體Dy擴散后晶界處Dy富集條紋更明顯、連續(xù),完整包裹各個主相晶粒。這種結構優(yōu)化也使低氧磁體各向異性場提高幅度大于高氧磁體。磁體中氧含量降低使富釹相在主相周邊均勻連續(xù)分布,為后續(xù)進入磁體內部的Dy元素提供連續(xù)的擴散通道,從而使磁體的Dy擴散量和矯頑力提高量進一步提高。

    Abstract:

    In present work, the influence of the oxygen content variation on the Dy increment and the coercivity increment in Dy grain boundary diffusion processed (GBDP) Nd-Fe-B sintered magnet was investigated. Various magnets including both high and low oxygen types were processed and the latter one showed higher increments either in Dy contents or in Hcj. Nine specimens with 0wt. % original Dy contents were compared after GBDP, and it was proved that decrease of oxygen is beneficial to Dy content and Hcj increase. Furthermore, Dy content gradient in each GBDP sample showed that the gap between the outer and interior region in low oxygen magnets were narrower. According to the EPMA figures, Dy-rich shells were more continuous and brighter and almost completely surrounded each matrix grains in low oxygen GBDP magnet. The optimization of the microstructure enabled the low oxygen GBDP sample to gain a higher anisotropic field increment. Decrease of oxygen lead to Nd-rich phase surround the matrix phase more homogeneously and continuously, providing a more continuous tunnel for Dy to diffuse into the magnet, ultimately inducing a further enhancements of Dy content and Hcj.

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程星華,李建,周磊,劉濤,喻曉軍,李波.氧含量對燒結釹鐵硼磁體Dy晶界擴散的影響研究[J].稀有金屬材料與工程,2019,48(6):2009~2013.[Cheng Xinghua, Li Jian, Zhou Lei, Liu Tao, Yu Xiaojun, Li Bo. Influence of Oxygen content on Dy grain boundary diffusion in Nd-Fe-B sintered magnets[J]. Rare Metal Materials and Engineering,2019,48(6):2009~2013.]
DOI:10.12442/j. issn.1002-185X.20171149

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  • 收稿日期:2017-12-14
  • 最后修改日期:2018-01-05
  • 錄用日期:2018-02-09
  • 在線發(fā)布日期: 2019-07-30
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