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脈沖周期對(duì)黃金電沉積層的影響
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1.中國地質(zhì)大學(xué)武漢珠寶學(xué)院;2.武漢工程科技學(xué)院

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中國地質(zhì)大學(xué)(武漢)珠寶檢測(cè)技術(shù)創(chuàng)新中心開放基金(CJHIXM-S201615)


Influence of Pulse Period of Bidirectional Pulse Electrodeposition Process on the Properties of Electroformed Layer of Gold
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1.China University of Geosciences,Gemmological Institution;2.Wuhan University of Engineering Science,School of Jewellery

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    摘要:

    在無氰黃金電沉積工藝的基礎(chǔ)上,利用雙向脈沖電源,經(jīng)過十個(gè)小時(shí)的電沉積可以得到質(zhì)量較好的黃金樣品。以脈沖周期為單一變量,通過單一變量試驗(yàn),利用掃描電鏡、X射線衍射儀以及維氏硬度計(jì)探討了黃金電沉積層的微觀形貌、平均晶粒尺寸以及維氏硬度值。結(jié)果顯示當(dāng)脈沖周期為45ms到75ms范圍內(nèi)時(shí),電沉積層的維氏硬度值可以達(dá)到117.0HV0.1,且電沉積層具有較強(qiáng)的(111)晶面的擇優(yōu)取向。較強(qiáng)的(111)晶面擇優(yōu)取向伴隨著電沉積層更加平整的微觀形貌以及更高的維氏硬度值。。

    Abstract:

    Electroformed gold layers were prepared by bidirectional pulse electrodeposition process, with thickness up to 150μm in 20h from cyanide-free bath. Through single variable experiment, which the pulse period was treated as a single variable, we studied the effect of pulse period on the properties of electroformed layer of gold using bidirectional pulse power. Scanning Electron Microscopy, X-ray Diffraction, and Vickers hardness test were used to research the surface mophology, average crystal size and hardness of electroformed gold layers. Results showed the microhardness of electroformed layer of gold is higher when pulse period changes between 45ms and 75ms, which can reach to 117HV0.1. Strong (111) preferred orientation can result in more flat micro surface and higher micohardness of electroformed gold layers.

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鄭利珊,袁心強(qiáng),雷婷.脈沖周期對(duì)黃金電沉積層的影響[J].稀有金屬材料與工程,2019,48(6):1797~1802.[Zheng Lishan, Yuan Xinqiang, Lei Ting. Influence of Pulse Period of Bidirectional Pulse Electrodeposition Process on the Properties of Electroformed Layer of Gold[J]. Rare Metal Materials and Engineering,2019,48(6):1797~1802.]
DOI:10.12442/j. issn.1002-185X.20171046

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  • 收稿日期:2017-11-19
  • 最后修改日期:2018-03-15
  • 錄用日期:2018-08-31
  • 在線發(fā)布日期: 2019-07-30
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