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617B鎳基高溫合金長期時(shí)效組織演變
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北京科技大學(xué)

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國家重點(diǎn)研發(fā)計(jì)劃(項(xiàng)目號(hào)2017YFB0305201)


Microstructure Evolution of Long-Term Aged 617B Ni-based Superalloy
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University of Science and Technology Beijing

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    摘要:

    617B是一種固溶強(qiáng)化型鎳基高溫合金,是700℃先進(jìn)超超臨界火電站的候選材料之一,通常使用狀態(tài)為固溶態(tài),使用溫度為700℃左右,因此研究其在近服役溫度范圍內(nèi)的長期時(shí)效組織演變對(duì)其在實(shí)際應(yīng)用中具有重要的意義。本文對(duì)617B合金在650℃、700℃、750℃分別時(shí)效至3000h并通過光學(xué)顯微鏡、場(chǎng)發(fā)射掃描電鏡以及能譜分析其在時(shí)效過程中的組織演變規(guī)律。經(jīng)研究發(fā)現(xiàn),在時(shí)效過程中617B合金中主要的析出相為γ"相、富Cr、Mo的M23C6。650℃,600h后開始析出γ"相,且隨著時(shí)效時(shí)間的延長以及溫度的提高發(fā)生一定程度的粗化。低于700℃時(shí)效,γ"相的粗化滿足傳統(tǒng)的LSW理論,而大于750℃長期時(shí)效則轉(zhuǎn)變?yōu)橐詧F(tuán)聚為主的粗化方式。晶界碳化由細(xì)小不連續(xù)分布的鋸齒狀逐漸粗化轉(zhuǎn)化為連續(xù)的網(wǎng)狀結(jié)構(gòu),晶內(nèi)碳化物析出增多。750℃高溫長期時(shí)效,碳化物可能存在與基體、γ"相之間的反應(yīng)。

    Abstract:

    617B is a solid-solution strengthened Ni-based superalloy, a candidate material for 700℃ A-USC power plant. It is always used in solution-anneal at about 700℃. So it is significant to research its microstructure evolution during aging at its service temperature rang form 650℃ to 750℃. In this work, the 617B alloy was exposed prolonged approximately 3000h at 650℃, 700℃, 750℃ respectively. The microstructure evolution had been characterized by optical microscope (OM), field emission scanning electron microscope (FESEM) and energy dispersive spectrometer (EDS). γ" phase and Cr, Mo-rich M23C6 were the major precipitates during aging treatment. γ" phase precipitated at about 650℃,600h and got coarsening with a prolonged time and an increasing temperature. The coarsening of γ" phase met the LSW theory below 700℃ aging but when exposed higher than 750℃, it was priority to coarsen by agglomeration. The carbides along grain boundaries were transformed into continuous network structure by the gradual coarsening of small serration carbides. And carbides within grains increased during aging. When alloy undergone 750℃ long-term aged, there are reactions between carbides, matrix and γ"phase.

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向雪梅.617B鎳基高溫合金長期時(shí)效組織演變[J].稀有金屬材料與工程,2019,47(3):865~872.[xiangxuemei. Microstructure Evolution of Long-Term Aged 617B Ni-based Superalloy[J]. Rare Metal Materials and Engineering,2019,47(3):865~872.]
DOI:10.12442/j. issn.1002-185X.20170675

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  • 收稿日期:2017-08-01
  • 最后修改日期:2017-09-06
  • 錄用日期:2017-09-12
  • 在線發(fā)布日期: 2019-04-10
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