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鋯管表面沉積Cr-TiAlSiN復合涂層的表面形貌與性能研究
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作者單位:

南華大學,機械工程學院

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通訊作者:

中圖分類號:

TG146.4+14

基金項目:

國家自然科學基金項目(面上項目,重點項目,重大項目);湖南省教育廳重點實驗室創(chuàng)新平臺開放基金項目


Research on?Micro-morphology and Performance of Cr-TiAlSiN Composite Coating Deposited on Zirconium Tube
Author:
Affiliation:

School of Mechanical Engineering,The university of south china

Fund Project:

National Major Projects of Science and Technology(2015ZX06004001-002-002);Innovation platform open fund project of Hunan education department key laboratory(16K076)

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    摘要:

    分別采用多弧離子鍍和中頻非平衡磁控濺射工藝,在鋯合金管材基體上制備Cr-TiAlSiN復合涂層。利用掃描電鏡對復合涂層的表面及截面微觀形貌進行觀察;利用Image J軟件對復合涂層進行孔隙率和表面大顆粒數(shù)目進行統(tǒng)計分析;利用彈簧拉壓試驗機對涂層的膜基結(jié)合強度進行測量;利用高溫熱處理爐對試樣進行800℃高溫抗氧化試驗和1200℃高溫淬火實驗。實驗結(jié)果表明:采用多弧離子鍍工藝所獲得的涂層表面大顆粒物質(zhì)比較多,但是孔隙率比較低,致使其高溫抗氧化性能較好。復合涂層膜基界面比較明顯且比較均勻,膜基結(jié)合強度較高,大于22.68Mpa,1200℃高溫淬火實驗側(cè)面表明采用多弧離子鍍工藝的涂層其膜基結(jié)合強度較好。

    Abstract:

    Abstract: Cr-TiAlSiN composite coatings were deposited on the substrate of zirconium alloys tubes by multi-arc ion plating and intermediate frequency unbalanced magnetron sputtering, respectively. The micro-morphology of surface and cross-section of the composite coatings was observed by a scanning electron microscopy; the porosity and the quantity of large particles on the surface were analyzed by Image J software; the adhesion strength between the coatings and substrate was measured by a?pull pressed?spring?testing machine; the samples were subjected to high temperature oxidation test at 800℃ and high temperature quenching test at 1200℃ by using a high temperature furnace. The results show that there are more large particles on the surface of the coatings deposited by multi-arc ion plating, but the porosity of that is relatively low, so that the high temperature oxidation resistance behavior is better. The interface of the composite coatings is relatively clear and uniform, and the adhesion strength between the coatings and substrate is relatively strong, both of which are higher than 22.68MPa. According to the high temperature quenching test at 1200℃, it also turns out from the side that the adhesion strength is better with the process of multi-arc ion plating.

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引用本文

周軍.鋯管表面沉積Cr-TiAlSiN復合涂層的表面形貌與性能研究[J].稀有金屬材料與工程,2019,48(1):85~90.[zhoujun. Research on?Micro-morphology and Performance of Cr-TiAlSiN Composite Coating Deposited on Zirconium Tube[J]. Rare Metal Materials and Engineering,2019,48(1):85~90.]
DOI:10.12442/j. issn.1002-185X.20170607

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  • 收稿日期:2017-07-10
  • 最后修改日期:2017-10-12
  • 錄用日期:2017-10-12
  • 在線發(fā)布日期: 2019-02-18
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