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微量CaO對Mg-2Zn-0.5Sr鎂合金顯微組織、力學(xué)性能及腐蝕性能的影響
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北京科技大學(xué)

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中國國家重點研發(fā)計劃(2016YFB0700303)、廣東省教育部產(chǎn)學(xué)研結(jié)合項目(2015B090901044)


Effect of trace CaO on microstructure, mechanical properties and corrosion behavior of Mg-2Zn-0.5Sr alloy
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School of Materials Science and Engineering,University of Science and Technology Beijing

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    摘要:

    本文主要研究了添加0.1 wt.% CaO和0.3 wt.% CaO對Mg-2Zn-0.5Sr顯微組織、力學(xué)性能及腐蝕性能的影響。光學(xué)顯微鏡(OM)、X射線衍射儀(XRD)及電子探針顯微分析儀(EPMA)分析了材料均勻化熱處理后的顯微組織和第二相的組成與分布,發(fā)現(xiàn)CaO顆粒的加入使Mg-2Zn-0.5Sr的晶粒尺寸明顯細化,而且CaO顆粒機械地富集于晶界及晶粒內(nèi)的第二相與基體之間。室溫拉伸試驗研究材料機械性能,CaO顆粒的加入可以提高材料強度,但添加0.1 wt.% CaO時材料的塑性降低,而添加0.3 wt.% CaO時材料的塑性也有所提高,延伸率達到10.9 ± 1.1%。Kokubo模擬體液中的動電位極化曲線表明添加CaO顆粒使腐蝕電位正移。浸泡失重實驗表明Mg-2Zn-0.5Sr的平均腐蝕速率為7.55 mm/year,添加0.1 wt.% CaO時腐蝕速率降低大約18.3%,添加0.3 wt.% CaO時腐蝕速率增高大約52%。CaO顆粒對顯微組織及機械性能的影響決定于晶粒細化和CaO顆粒在第二相與基體之間機械富集的綜合影響,而其對生物腐蝕行為的影響主要決定于晶粒細化及CaO顆粒在溶液中反應(yīng)對致密穩(wěn)定CaHPO4保護膜生成的促進作用。Mg-2Zn-0.5Sr/0.1CaO表現(xiàn)出較高的強度和較佳的耐腐蝕性能,是生物醫(yī)用材料中的一種較好選擇。

    Abstract:

    Effect of the addition of trace CaO particles (0.1 and 0.3wt. %) into Mg-2Zn-0.5Sr on the microstructure, mechanical properties, and bio-corrosion behaviors was investigated. Microstructures and the composition and distribution of the second phases of Mg-2Zn-0.5Sr-xCaO composites (x=0, 0.1 and 0.3wt. %) were characterized by optical microscope (OM), X-ray diffraction (XRD), electron probe microanalyzer (EPMA), which indicated that the addition of CaO particles can lead to grain refinement and the CaO particles were mostly enriched between the second phases at grain boundaries and the α-Mg matrix. Results of mechanical properties investigated by tensile tests at room temperature show that the addition of CaO particles can improve the strength. However when adding 0.1 wt.% CaO particles, the plasticity decreases, but when adding 0.3 wt.% CaO particles, the plasticity increases. Electrochemical tests show that the corrosion potential (Ecorr) of Mg-2Zn-0.5Sr/CaO composites significantly shifts toward a more positive direction when CaO particles were added into Mg-2Zn-0.5Sr. Immersion tests show that the average corrosion rate of Mg-2Zn-0.5Sr is 7.55 mm/year. And when adding 0.1 wt.% CaO, the corrosion rate decreases by about 18.3%, and when adding 0.1 wt.% CaO, the corrosion rate increases by about 52%. Both the microstructure and mechanical properties can be attributed to grain refinement and the mechanical bonding of CaO particles with the second phases and the α-Mg matrix. The bio-corrosion behaviors can be attributed to grain refinement and the formation of table and dense CaHPO4 protective film due to the reaction of CaO.

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李建興,張源,李靜媛,謝建新.微量CaO對Mg-2Zn-0.5Sr鎂合金顯微組織、力學(xué)性能及腐蝕性能的影響[J].稀有金屬材料與工程,2019,48(2):463~472.[Jian-Xing Li, Yuan-Zhang, Jing-Yuan Li, Xie Jianxin. Effect of trace CaO on microstructure, mechanical properties and corrosion behavior of Mg-2Zn-0.5Sr alloy[J]. Rare Metal Materials and Engineering,2019,48(2):463~472.]
DOI:10.12442/j. issn.1002-185X.20170472

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  • 收稿日期:2017-06-02
  • 最后修改日期:2017-11-08
  • 錄用日期:2017-11-08
  • 在線發(fā)布日期: 2019-03-15
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