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Sr元素對Mg-Zn-Ca合金非晶形成能力和耐蝕性的影響
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西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院,西安工業(yè)大學(xué)材料與化工學(xué)院

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TG146. 22

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國家自然科學(xué)基金資助(項目號51201120),陜西省科技統(tǒng)籌創(chuàng)新工程計劃項目(2016KTZDGY-04-01), 陜西省教育廳重點實驗室項目


Effect of Sr element on the glass forming ability and corrosion properties of bulk Mg-Zn-Ca alloys
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School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering,School of Materials Science and Chemical Engineering

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    摘要:

    為改善Mg-Zn-Ca合金的非晶形成能力,本文采用銅模噴鑄法制備了不同Sr含量的Mg-Zn-Ca-Sr合金2 mm和4mm棒材試樣。利用XRD、SEM、DSC和電化學(xué)測試方法研究了Sr元素對Mg-Zn-Ca合金非晶形成能力和在模擬體液中耐蝕性的影響。結(jié)果表明,Mg65Zn30Ca5-xSrx(x=0,0.5,1.0,1.5, at%)合金的2mm棒材試樣組織均為非晶態(tài),而4mm棒材試樣均是由非晶和晶體相(Mg和MgZn相)組,但晶體相的體積分?jǐn)?shù)和尺寸隨著Sr元素添加量的增加而減少,即合金的非晶形成能力提高,其中,Mg65Zn30Ca4Sr1合金非晶形成能力最強。電化學(xué)腐蝕測試結(jié)果表明隨著Sr含量增多,合金的腐蝕電位向正向移動,腐蝕電流密度減小,合金的耐蝕性逐漸增強,2mm棒材試樣中Mg65Zn30Ca4Sr0.5合金的耐蝕性最好,4mm棒材試樣中Mg65Zn30Ca4Sr1合金的耐蝕性最強。

    Abstract:

    In order to improve the glass forming ability of Mg-Zn-Ca alloy, 2mm and 4mm rod samples of Mg-Zn-Ca-Sr alloys with different amount of Sr were prepared by copper mould injection method. Effects of Sr addition on glass forming ability and corrosion properties in simulated body fluids of Mg-Zn-Ca alloys were studied by means of X-ray diffraction, scanning electron microscopy, differential scanning calorimeter and electrochemical test. Results showed that with the increasing content of Sr element, the 2mm rod samples were all in completely amorphous state. While the microstructure of 4 mm rod samples were composed of amorphous phase and crystalline Mg and MgZn phases. However, the volume fraction and particle size were decreased with increasing addition of Sr element, which indicated that the glass forming ability of Mg-Zn-Ca alloy was enhanced with Sr element addition. Mg65Zn30Ca4Sr1 alloy exhibited the highest glass forming ability. The results of electrochemical test demonstrated that Sr-doped samples showed more positive corrosion potential and smaller corrosion current density, which suggested that the corrosion resistance was improved with increasing addition of Sr element. The corrosion resistance of Mg65Zn30Ca4.5Sr0.5 alloy was the highest among the 2mm rod samples, while the corrosion resistance of Mg65Zn30Ca4Sr1 alloy was the best among the 4mm rod samples.

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王建利,萬銀,朱美玲,馬志軍,郭永春,楊忠,李建平. Sr元素對Mg-Zn-Ca合金非晶形成能力和耐蝕性的影響[J].稀有金屬材料與工程,2018,47(7):2151~2158.[WANG Jian-Li, WAN Yin, Zhu Mei-ling, MA Zhijun, Guo Yong-chun, Yang Zhong, LI Jian-Ping. Effect of Sr element on the glass forming ability and corrosion properties of bulk Mg-Zn-Ca alloys[J]. Rare Metal Materials and Engineering,2018,47(7):2151~2158.]
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  • 收稿日期:2017-05-17
  • 最后修改日期:2017-07-18
  • 錄用日期:2017-08-18
  • 在線發(fā)布日期: 2018-10-10
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