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La2O3:Sm3+納米發(fā)光材料的燃燒法合成及其性能研究
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湖南大學(xué)物理與微電子科學(xué)學(xué)院

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TG174

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國(guó)家自然科學(xué)基金資助(61505052, 61176116)


Study on Synthesis and properties of nano luminescent materials La2O3:Sm3+ by combustion method
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School of Physics and Electronics,Hunan University

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    摘要:

    通過(guò)燃燒法制備了La2O3:Sm3+納米材料,用XRD和TEM對(duì)其形貌結(jié)構(gòu)進(jìn)行了表征和分析,并研究了其發(fā)光性質(zhì)。結(jié)果表明:La2O3:Sm3+納米材料為六角結(jié)構(gòu),顆粒尺寸大約為34 nm; Sm3+的摻雜引起其衍射峰的位置發(fā)生略微的右移; Sm3+的本征激發(fā)帶位于411 nm左右;在近紫外光(411 nm)的激發(fā)下,觀察到 4G5/2 → 6H5/2 (568 nm)、 4G5/2 → 6H7/2 (611 nm, 強(qiáng)度最高) 和 4G5/2 → 6H9/2 (654 nm)三個(gè)主發(fā)射峰;發(fā)射光譜表明La2O3:Sm3+中Sm3+離子的格位對(duì)稱性較低;材料樣品的衰減壽命約為202 us,色度坐標(biāo)大約為(0.5849, 0.4143)。

    Abstract:

    Nanomaterials La2O3:Sm3+was prepared by combustion synthesis. The morphology and structure were characterized and analyzed by TEM and XRD. The luminescent properties were also investigated. The results were indicated that the mean particle size of La2O3:Sm3+ nanomaterials with hexagonal structure were approximately 34 nm. Because of the Sm3+ doping, the position of diffraction peaks of La2O3:Sm3+ moved to the right slightly; It was observed that intrinsic excitation band of Sm3+ was located in around 411 nm; Under the 411 nm excitation, the major emission peaks at 4G5/2 → 6H5/2 (568 nm),4G5/2 → 6H7/2 (611 nm, the highest intensity) and 4G5/2 → 6H9/2 (654 nm) were observed. The emission spectrum indicated the location of the Sm3+ ions were asymmetric. The decay lifetime of the Sm3+ ions was about 202 μs; The chromaticity coordinate was approximately (0.5849, 0.4143).

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張清君,劉晃清,王玲玲. La2O3:Sm3+納米發(fā)光材料的燃燒法合成及其性能研究[J].稀有金屬材料與工程,2019,48(1):133~136.[Zhang Qingjun, Liu Huangqing, Wang Lingling. Study on Synthesis and properties of nano luminescent materials La2O3:Sm3+ by combustion method[J]. Rare Metal Materials and Engineering,2019,48(1):133~136.]
DOI:10.12442/j. issn.1002-185X.20170386

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  • 收稿日期:2017-05-10
  • 最后修改日期:2017-06-05
  • 錄用日期:2017-06-26
  • 在線發(fā)布日期: 2019-02-18
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