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S280新型超高強度不銹鋼中一種新的析出相的研究
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作者單位:

1.北京航空航天大學;2.北京航空材料研究院

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中圖分類號:

TG142.1

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A TRANSMISSION ELETRON MICROSCOPY STUDY ON A NEW TYPE OF ULTRAHIGH STRENGTH STAINLESS STEEL S280
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Affiliation:

1.Beihang University;2.Beijing Institute of Aeronautical Materials

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    摘要:

    為了防止涂層工藝產生的副作用,開發(fā)了一種環(huán)保型的飛機起落架用超高強度不銹鋼S280。新超高強度不銹鋼S280具有等于或高于常規(guī)超高強度鋼的力學性能,且有更好的耐腐蝕性。通過熱處理工藝實驗確定了超高強度不銹鋼S280合適的熱處理工藝(1080 ℃,保溫1 h,油冷;-73 ℃,2 h,空氣中回到室溫:540℃,4 h,空冷)。S280鋼熱處理后,強度大于1900 MPa,K1C大于90 MPa?m1/2。利用透射電子顯微鏡和高分辨電子顯微鏡研究了540℃和600℃時效態(tài)的S280新型超高強度不銹鋼微觀組織結構。結果表明:S280鋼540℃時效狀態(tài),在高密度位錯的板條狀馬氏體基體上析出彌散細小的強化相,一種是已為很多研究報道的超高強度鋼中強化相Fe2Mo[1],另一種析出相是Cr2C,目前還沒有相關報道。本文首次發(fā)現了這種強化相,測定了其與馬氏體的晶體學取向關系為: ( 1 -1 0 )M // (-1 2 -1 )Cr2C,[ 1 1 1 ]M // [ 1 1 1 ]Cr2C。 S280鋼在600℃時效態(tài)也析出這兩種Cr2C和Fe2Mo相,與540℃時效態(tài)相比,只是其有所長大。利用X射線能譜分析法對Cr2C析出相進行了分析,結果表明,Cr2C析出相中Cr和Mo的含量較高。

    Abstract:

    The ultra-high-strength stainless steel with high strength and toughness, high inherent fatigue strength and good corrosion resistance can be mainly used in some load- bearing components, such as landing gear, gas turbine engine shaft, and wheel bolts that working under corrosion environment. An environmental friendly ultra high strength stainless steel S280 for a new type of aircraft landing gear was developed in order to avoid the toxic effect of protective coating processes. The new ultra high strength stainless steel S280 has mechanical properties equal to, or better than conventional ultrahigh strength steels with the added benefit of modest corrosion resistance. By heat treatment process experiments and mechanical tests, the appropriate heat treatment process of S280 steel (Heating to 1080 ℃,holding at heat for one hour, and quenching in oil, cooling to -73℃, holding at this temperature for two hours, and warming in air to room temperature and then heating to 540℃, holding at heat for four hours, and cooling in air) was found in this paper. After heat treated under the appropriate heat treatment process,S280 steel can get good comprehensive performance, with the strength of 1900MPa, and KIC of 90MPa?m1/2. The new ultrahigh strength stainless steel S280, which apply low-carbon martensitic transformation hardening and aging strengthening superimposed, has high performance and can replace the existing Aer-Met100,300M steel material used for aircraft landing gear. The microstructures of new ultrahigh strength stainless steel S280 after thermal ageing at 540℃ and 600℃ was investigated by optical microscopy, transmission electron microscopy (TEM) and high-resolution electron microscopy (HREM).The results show that the S280 steel aged at 540℃ has desirable microstructures, which is fine lath martensite matrix with high-density dislocation and finely dispersed precipitate strengthening phase, and film-like reversed austenite precipitated from the boundary of martensite. The strengthening phases of the steel include Fe2Mo[1], Fe3C and Cr2C. There is no related report about that Cr2C precipitated from ultrahigh strength steel as a strengthening phase. In this paper, it was firstly discovered. And the crystallographic orientation relationship between Cr2C and matrix was measured: (1 -1 0 )M // ( -1 2 -1 )Cr2C, [ 1 1 1 ]M // [ 1 1 1 ]Cr2C The steel aged at the different temperature of 600℃ and 540℃ have the same precipitated phases Cr2C and Fe2Mo. The precipitated phases are relatively bigger than that of sample aged at 540℃.The strengthening phases of S280 steel have a high content of Cr and Co analyzed by energy spectrum analysis (EDS).

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鐘錦巖,張業(yè)勤,韓雅芳. S280新型超高強度不銹鋼中一種新的析出相的研究[J].稀有金屬材料與工程,2019,48(1):116~122.[ZHONGJINYAN, Zhang Yeqin, Han Yafang. A TRANSMISSION ELETRON MICROSCOPY STUDY ON A NEW TYPE OF ULTRAHIGH STRENGTH STAINLESS STEEL S280[J]. Rare Metal Materials and Engineering,2019,48(1):116~122.]
DOI:10.12442/j. issn.1002-185X.20170383

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  • 收稿日期:2017-05-10
  • 最后修改日期:2017-06-20
  • 錄用日期:2017-11-08
  • 在線發(fā)布日期: 2019-02-18
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