2相組成。ZK60-1Nd鎂合金在3.5wt % 的NaCl水溶液中的腐蝕速率為0.2 mg.cm-2.h-1;經(jīng)過(guò)400 ℃保溫96 h后,部分共晶相熔斷成尺寸約為0.5 μm的顆粒,腐蝕速率降低到0.1 mg.cm-2.h-1;經(jīng)過(guò)500 ℃保溫8.0 h,網(wǎng)狀共晶相熔化成分散塊狀,基體中細(xì)小棒狀MgZn2相溶解消失,Nd,Zn和Zr元素在基體中含量增加且分布均勻,腐蝕速率達(dá)到最低,為0.03 mg.cm-2.h-1。其耐蝕性能改善的主要原因?yàn)棣?Mg基體中固溶態(tài)Nd元素含量的增加導(dǎo)致合金自腐蝕電位提高以及基體α-Mg中腐蝕微電偶數(shù)目的減少。"/>

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ZK60-1Nd鎂合金的組織結(jié)構(gòu)及腐蝕行為
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遼寧科技大學(xué) 材料與冶金學(xué)院,遼寧科技大學(xué) 材料與冶金學(xué)院,遼寧科技大學(xué) 材料與冶金學(xué)院,遼寧科技大學(xué) 材料與冶金學(xué)院,遼寧科技大學(xué) 材料與冶金學(xué)院

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51374128)


Microstructure And Corrosion Behavior Of ZK60-1Nd Magnesium Alloy
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University of Science and Technology Liaoning,University of Science and Technology Liaoning,University of Science and Technology Liaoning,University of Science and Technology Liaoning,University of Science and Technology Liaoning

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    通過(guò)掃描電鏡(SEM),電化學(xué)工作站和鹽水浸泡失重法研究了ZK60-1Nd鎂合金的組織結(jié)構(gòu)及在3.5wt % NaCl水溶液中的腐蝕行為。結(jié)果表明:ZK60-1Nd鎂合金主要由基體α-Mg相,沿晶界分布的含有稀土Nd的粗大網(wǎng)狀共晶組織以及在基體中彌散分布的細(xì)小棒狀MgZn2相組成。ZK60-1Nd鎂合金在3.5wt % 的NaCl水溶液中的腐蝕速率為0.2 mg.cm-2.h-1;經(jīng)過(guò)400 ℃保溫96 h后,部分共晶相熔斷成尺寸約為0.5 μm的顆粒,腐蝕速率降低到0.1 mg.cm-2.h-1;經(jīng)過(guò)500 ℃保溫8.0 h,網(wǎng)狀共晶相熔化成分散塊狀,基體中細(xì)小棒狀MgZn2相溶解消失,Nd,Zn和Zr元素在基體中含量增加且分布均勻,腐蝕速率達(dá)到最低,為0.03 mg.cm-2.h-1。其耐蝕性能改善的主要原因?yàn)棣?Mg基體中固溶態(tài)Nd元素含量的增加導(dǎo)致合金自腐蝕電位提高以及基體α-Mg中腐蝕微電偶數(shù)目的減少。

    Abstract:

    Microstructure and the corrosion behavior of ZK60-1Nd magnesium alloy in 3.5 wt % NaCl aqueous solution was studied by scanning electron microscope (SEM) , electrochemical workstation and brine weight loss method. The results indicate that the as-cast microstructure of ZK60-1Nd alloy is mainly composed of matrixα-Mg, a coarse network eutectic phase containing rare earth Nd distribute along the grain boundaries and the distribution of fine MgZn2 phase in the matrix. The corrosion rate of ZK60-1Nd magnesium alloy in 3.5 wt % NaCl aqueous solution was 0.2 mg ? cm-2 ? h-1 in NaCl solution. After homogenization at 300 ℃ for 8.0 h , the microstructure was improved;after annealing at 400 ℃ for 96 h, A portion of the eutectic phase is fused to a particle with a maximum size of 1.5 μm and the corrosion rate is reduced to 0.1 mg.cm-2.h-1; After annealing at 500 ℃ for 8.0 h , fishbone eutectic phase composition of patchy, the MgZn2 phase is dissolvedSintoSmatrix , the contents of Nd, Zn and Zr were increased and the distribution was uniform in the matrix , corrosion rate reached a minimum of 0.03 mg.cm-2.h-1. The main reason for the improvement of corrosion resistance is that the increase of the content of solid solution Nd in matrix α-Mg lead to the improvement of corrosion potential and the decrease in the number of micro galvanic corrosion.

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褚旭,王忠軍,張濤,王冬曉,王洪斌. ZK60-1Nd鎂合金的組織結(jié)構(gòu)及腐蝕行為[J].稀有金屬材料與工程,2018,47(5):1429~1436.[Chu Xu, Wang Zhongjun, Zhang Tao, Wang Dongxiao, Wang Hongbin. Microstructure And Corrosion Behavior Of ZK60-1Nd Magnesium Alloy[J]. Rare Metal Materials and Engineering,2018,47(5):1429~1436.]
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  • 收稿日期:2017-05-09
  • 最后修改日期:2017-08-28
  • 錄用日期:2017-09-11
  • 在線(xiàn)發(fā)布日期: 2018-06-08
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