0.29Ni0.16C0.06韌性相含量增加,在涂層界面處存在過渡層Ni,并以塑性變形的方式釋放了更多沉積時產(chǎn)生的熱應(yīng)力,因而涂層裂紋明顯減少。復(fù)合涂層的峰值硬度(1186HV0.05)雖略低于單涂層,但該涂層具有最小的摩擦系數(shù)(0.2462),1h磨損量僅為單涂層的1/3,因此表現(xiàn)出更好的耐磨性能,其主要磨損機制為磨粒磨損和疲勞磨損。"/>

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碳化鉻基金屬陶瓷電火花沉積涂層的微觀組織與性能
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1.中南大學(xué);2.湖南人文科技學(xué)院

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湖南省應(yīng)用基礎(chǔ)研究重點項目(2016JC2007)


Microstructure and properties of chromium carbide based metal-ceramic coatings by electro-spark deposition
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1.Central South University;2.Hunan University of Humanities,Science and Technology

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    摘要:

    采用電火花沉積分別制備了碳化鉻基金屬陶瓷單涂層和碳化鉻基金屬陶瓷/Ni復(fù)合涂層。采用X射線衍射儀(XRD)、掃描電鏡(SEM)、顯微硬度計和摩擦磨損試驗機對比研究了單涂層和復(fù)合涂層的物相、微觀組織結(jié)構(gòu)、顯微硬度和摩擦磨損性能。結(jié)果表明,兩種涂層組織結(jié)構(gòu)致密,與基體呈良好的冶金結(jié)合,并在涂層內(nèi)形成了納米晶的微觀組織。復(fù)合涂層中FeCr0.29Ni0.16C0.06韌性相含量增加,在涂層界面處存在過渡層Ni,并以塑性變形的方式釋放了更多沉積時產(chǎn)生的熱應(yīng)力,因而涂層裂紋明顯減少。復(fù)合涂層的峰值硬度(1186HV0.05)雖略低于單涂層,但該涂層具有最小的摩擦系數(shù)(0.2462),1h磨損量僅為單涂層的1/3,因此表現(xiàn)出更好的耐磨性能,其主要磨損機制為磨粒磨損和疲勞磨損。

    Abstract:

    The chromium carbide based metal-ceramic monolithic coating and chromium carbide based metal-ceramic/Ni composite coating were prepared by electro-spark deposition. The phase compositions, microstructure, microhardness and tribological properties of monolithic and composite coatings were characterized comparatively by X-ray diffraction (XRD), scanning electron microscopy (SEM), microhardness test, friction and wear test. The results indicate that the two kinds of coatings are dense, metallurgically bonded with substrate and have nanocrystalline microstructure. In composite coating, the content of FeCr0.29Ni0.16C0.06plastic phase increases and Ni transition layer exists at the interface, which could release thermal stress via plastic deformation, therefore the number of cracks reduce significantly. Meanwhile, the maximum microhardness of composite coating (1186HV0.05) is slightly lower than that of monolithic, but it displays the minimum friction coefficient (0.2462), and the wear mass of 1h is only 1/3 of that of monolithic, therefore it displays better tribological properties and the main wear mechanisms are abrasive and fatigue wear.

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張怡,陳志國,魏祥,汪力,侯志偉,楊威.碳化鉻基金屬陶瓷電火花沉積涂層的微觀組織與性能[J].稀有金屬材料與工程,2019,48(2):601~607.[Zhang Yi, Chen Zhiguo, Wei Xiang, Wang Li, Hou Zhiwei, Yang Wei. Microstructure and properties of chromium carbide based metal-ceramic coatings by electro-spark deposition[J]. Rare Metal Materials and Engineering,2019,48(2):601~607.]
DOI:10.12442/j. issn.1002-185X.20170355

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  • 收稿日期:2017-05-02
  • 最后修改日期:2017-10-16
  • 錄用日期:2017-11-09
  • 在線發(fā)布日期: 2019-03-15
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