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Nb、Si、B含量的聯(lián)動(dòng)調(diào)整對(duì)Finemet型薄帶結(jié)構(gòu)及性能的影響
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作者單位:

1.河北工業(yè)大學(xué);2.天津中晟泰新能源科技有限公司

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中圖分類(lèi)號(hào):

TG146.4+

基金項(xiàng)目:

國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51671078,51271072),國(guó)家自然科學(xué)青年基金項(xiàng)目(51301056),河北省自然科學(xué)(E2015202008)


Effect on Structure and Properties of Finemet-type Ribbon by Collaboratively Adjusting Nb, Si, B
Author:
Affiliation:

1.School of Materials Science and Engineering,Hebei University of Technology;2.Tian Jin Sun Hope New Energy Technology co,Ltd,Tianjin

Fund Project:

National Natural Science Foundation of China (Project No. 51671078,51271072), National Natural Science Youth Foundation(51301056), Natural Science of Hebei Province (E2015202008)

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    摘要:

    本文用V部分替代Nb并適當(dāng)調(diào)整Si與B的含量,通過(guò)單輥快淬技術(shù)及退火工藝制備了原始成分為Fe73Si15Nb3B8Cu1和優(yōu)化成分為Fe73Si15.5Nb1.1V2.4B7Cu1的Finemet型非晶納米晶薄帶。利用X射線(xiàn)衍射儀、透射電子顯微鏡、磁性能測(cè)試儀研究了薄帶的結(jié)構(gòu)及磁性能。結(jié)果表明:兩種快淬態(tài)薄帶主要為非晶結(jié)構(gòu),合金具有良好的非晶形成能力;采用Luborsky法評(píng)價(jià)薄帶韌性,發(fā)現(xiàn)含V的快淬態(tài)薄帶的斷裂應(yīng)變?chǔ)藅為5.05×10-2,其韌性較差;兩種退火態(tài)薄帶中的納米晶晶粒大小分別約為14.8 nm與13.2 nm;與原始成分薄帶相比,含V薄帶的居里溫度Tc,晶化起始溫度Tx1有少量降低;含V薄帶的飽和磁化強(qiáng)度略低于原始薄帶,但是其矯頑力較小,其環(huán)形磁芯樣品靜態(tài)初始磁導(dǎo)率為1.269×105、靜態(tài)損耗為1.748 J/m3,動(dòng)態(tài)測(cè)試顯示,隨著頻率的增加,含V薄帶損耗較原始薄帶小的優(yōu)勢(shì)更加明顯。

    Abstract:

    In this paper, the Finemet-type amorphous-nanocrystalline ribbons with original Fe73Si15Nb3B8Cu1 and optimized composition Fe73Si15.5Nb1.1V2.4B7Cu1 substituted partial Nb for V as well as appropriately adjusted Si and B were prepared by single-roller rapid quenching and isothermal annealing technology. The microstructure and magnetic properties of the ribbons were studied by X ray diffraction, transmission electron microscopy and magnetic performance testers. The results show that two types of as-spun ribbons are mainly composed of amorphous phase, meaning that two kinds of alloys have good amorphous forming ability; According to Luborsky principle, the fracture srain λt is 5.05×10-2, which indicates that the toughness is poor; The nanocrystalline grain size of two kinds of annealed ribbons are 14.8 nm and 13.2 nm, respectively; Compared with the original composition ribbons,Curie temperature Tc and first crystallization temperature Tx1 of V-containing ribbons are slightly decreased; While the saturation magnetization of the V-containing ribbon is slightly lower than that of the V-free ribbon, the coercivity is smaller, initial permeability and static loss of the ring-shaped V-containing magnetic core samples reach 1.269×105 and 1.748 J/m3 respectively, and their AC iron loss advantage is more and more obvious than that of V-free ones with increasing frequency.

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杜帥龍,張策,邊璐鵬,孫繼兵,張 磊,步紹靜. Nb、Si、B含量的聯(lián)動(dòng)調(diào)整對(duì)Finemet型薄帶結(jié)構(gòu)及性能的影響[J].稀有金屬材料與工程,2018,47(11):3548~3553.[Du shuailong, Zhang Ce, Bian Lupeng, Sun Jibing, Zhang Lei, Bu shaojing. Effect on Structure and Properties of Finemet-type Ribbon by Collaboratively Adjusting Nb, Si, B[J]. Rare Metal Materials and Engineering,2018,47(11):3548~3553.]
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  • 收稿日期:2017-03-14
  • 最后修改日期:2018-11-16
  • 錄用日期:2017-06-23
  • 在線(xiàn)發(fā)布日期: 2018-12-19
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