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Nb含量對(duì)機(jī)械合金化Cu-Nb合金晶粒細(xì)化和力學(xué)性能的影響
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中國(guó)計(jì)量大學(xué)材料科學(xué)與工程學(xué)院,中國(guó)計(jì)量大學(xué)材料科學(xué)與工程學(xué)院,中南大學(xué)

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中國(guó)自然科學(xué)基金青年基金


Effect of Nb Solute Concentration on Crystallite Size Refinement and Strength Enhancement in Mechanical Alloyed Cu-Nb Alloys
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College of Materials Science and Engineering,China Jiliang University,College of Materials Science and Engineering,China Jiliang University,School of Materials Science and Engineering,Central South University

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    摘要:

    采用機(jī)械合金化法制備了Cu-xNb(x=0-30%)合金粉末,通過(guò)X射線衍射儀(XRD)、金相顯微鏡(OM)、掃描電鏡(SEM)、透射電鏡(TEM)觀察和顯微硬度測(cè)量分析了Nb溶質(zhì)含量對(duì)粉末晶粒細(xì)化過(guò)程以及力學(xué)性能的影響。結(jié)果表明,盡管Nb與Cu的平衡固溶度接近為0,經(jīng)100h球磨后,Nb在Cu中的最大固溶量可達(dá)約11wt%。隨著Nb含量的增加,Cu-Nb合金粉末的晶粒細(xì)化能力提高。這是由于隨著偏析至位錯(cuò)處的溶質(zhì)原子數(shù)量增加,合金的回復(fù)過(guò)程得到抑制,因此有利于晶粒尺寸的減小。Cu-30wt%Nb合金球磨100h后Cu相平均晶粒尺寸減小至約6nm。此外,球磨Cu-Nb合金粉末的顯微硬度隨著Nb含量的增加而提高,其強(qiáng)化機(jī)制主要為細(xì)晶強(qiáng)化和固溶強(qiáng)化。

    Abstract:

    Cu-Nb alloys with Nb concentration ranging from 0-30wt% were prepared by mechanical alloying (MA) at room temperature. The effects of Nb content on the crystalline refinement process and mechanical property of the immiscible Cu-Nb system have been investigated by X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray detection, optical microscopy, transmission electron microscopy and microhardness measurement. It is found that the completed dissolution of Nb in Cu can be achieved in the samples with Nb content less than ~11wt% after 100 h milling, although the equilibrium solubility level is nearly zero. The grain size refinement capability of MA-ed Cu-Nb powders enhances with increasing Nb content up to 30wt%. This is because the susceptibility to recovery process becomes reduced, when the amount of Nb solutes segregated into the dislocation of Cu phase is increased. For the 100 h milled Cu-30wt%Nb powders, the average Cu grain size is only ~6nm. The microhardness of the samples shows an enhancement with increasing Nb concentration. The main strengthening mechanisms of the MA-ed Cu-Nb alloys are linked to the grain size reduction and the dissolution of Nb into Cu matrix.

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雷若姍,陳廣潤(rùn),汪明樸. Nb含量對(duì)機(jī)械合金化Cu-Nb合金晶粒細(xì)化和力學(xué)性能的影響[J].稀有金屬材料與工程,2018,47(9):2607~2614.[Ruoshan Lei, Guangrun Chen, Mingpu Wang. Effect of Nb Solute Concentration on Crystallite Size Refinement and Strength Enhancement in Mechanical Alloyed Cu-Nb Alloys[J]. Rare Metal Materials and Engineering,2018,47(9):2607~2614.]
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  • 收稿日期:2017-02-27
  • 最后修改日期:2017-08-07
  • 錄用日期:2017-08-16
  • 在線發(fā)布日期: 2018-11-01
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