4(Te,Sb)低熔點共晶相的數(shù)量不斷減少,520℃~530℃范圍內(nèi)吸熱峰峰值連續(xù)上升,晶界處Si相組織形貌由針片狀、多邊形狀與長棒狀演變?yōu)槎贪魻?、橢圓狀與球狀,球形平均粒徑僅為9μm;Si、Mg元素溶入初生α-Al基體的數(shù)量與密度、淬火瞬間Si相的固溶過飽和度隨之增加。聚乙二醇淬火介質(zhì)下經(jīng)545℃固溶20h與170℃時效10h,合金材料平均抗拉強度、屈服強度、延伸率、斷面收縮率與維氏硬度高達360MPa、307MPa、10.4%、13.8%與122,斷口表面以韌窩斷裂為主,伴生少量沿晶斷裂帶,Mg2Si強化相平均長度約為224nm。"/>

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Te、Sb對ZL114A合金T6態(tài)微觀組織與力學性能的影響
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1.中國航空工業(yè)集團公司北京航空材料研究院;2.北京宇航系統(tǒng)工程研究所

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中國航空工業(yè)集團公司北京航空材料研究院基金資助(基金號KJSC160206)


Study on Microstructure and Mechanical Properties of ZL114A Alloy in T6 State Bearing Te and Sb
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Beijing Institute of Aeronautical Materials

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    摘要:

    通過在ZL114A合金熔煉過程添加Te、Sb元素完成了硅相變質(zhì)處理,利用電感耦合法(ICP)測定了材料的化學成分,分別采用差熱分析(DSC)、萬能試驗機、金相顯微鏡(OM)、掃描電鏡(SEM)、能譜分析(EDS)與透射電鏡(TEM)全面分析了合金在不同T6熱處理態(tài)下的力學性能、晶界Si相形貌與組織演化規(guī)律。結(jié)果表明,隨著固溶/時效溫度的增加,晶界處Te、Sb元素溶入初生α-Al基體內(nèi)部的數(shù)量與密度連續(xù)增加,晶界處Al4(Te,Sb)低熔點共晶相的數(shù)量不斷減少,520℃~530℃范圍內(nèi)吸熱峰峰值連續(xù)上升,晶界處Si相組織形貌由針片狀、多邊形狀與長棒狀演變?yōu)槎贪魻?、橢圓狀與球狀,球形平均粒徑僅為9μm;Si、Mg元素溶入初生α-Al基體的數(shù)量與密度、淬火瞬間Si相的固溶過飽和度隨之增加。聚乙二醇淬火介質(zhì)下經(jīng)545℃固溶20h與170℃時效10h,合金材料平均抗拉強度、屈服強度、延伸率、斷面收縮率與維氏硬度高達360MPa、307MPa、10.4%、13.8%與122,斷口表面以韌窩斷裂為主,伴生少量沿晶斷裂帶,Mg2Si強化相平均長度約為224nm。

    Abstract:

    The silicon modification was prepared by adding Te and Sb elements in the smelting process. The chemical composition of the material was determined by inductively coupled method, the mechanical properties, morphology and microstructural evolution of silicon under different T6 states were analyzed by DSC, OM, SEM, EDS, TEM and Universal testing machine. The results show that the number and density of Te, Sb and Si, Mg elements dissolve in the primary α-Al matrix and the endothermic peak among from 520℃ to 530℃ rises with the increase of the solid solution and aging temperature, together with an increased solution supersaturation of silicon in the quenching moment. Whereas, the quantity of Al4(Te,Sb) eutectic phase reduces continuously, the morphology of silicon particles change from pin-like, polygonal and long-rod to short-rod like, oval and spherical, the average size is merely 9 μm. The average tensile strength, yield strength, elongation, reduction of area and Vickers hardness after solidifing at 545℃ for 20h and aging at 170℃ for 10h with the polyethylene glycol quenching medium are 360MPa, 307MPa, 10.4%, 13.8% and 122, dimple morphology is the dominated fracture surface, accompanied by some intergranular fracture zone, and the average length of Mg2Si phase is about 224nm.

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樊振中,王端志,王鯤鵬,熊艷才,陸政,鄭衛(wèi)東. Te、Sb對ZL114A合金T6態(tài)微觀組織與力學性能的影響[J].稀有金屬材料與工程,2018,47(12):3880~3886.[fanzhenzhong, Wang Duanzhi, Wang Kunpeng, Xiong Yancai, Lu Zheng, Zheng Weidong. Study on Microstructure and Mechanical Properties of ZL114A Alloy in T6 State Bearing Te and Sb[J]. Rare Metal Materials and Engineering,2018,47(12):3880~3886.]
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  • 收稿日期:2016-12-30
  • 最后修改日期:2018-05-30
  • 錄用日期:2018-06-15
  • 在線發(fā)布日期: 2019-01-04
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