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Hastelloy N合金表面激光熔覆NiCoCrAlY涂層在LiF-NaF-KF熔鹽中的腐蝕行為研究
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南華大學,南華大學,中國科學院上海應用物理研究所,南華大學,南華大學

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TG156.99

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國家自然科學基金(91326114)、湖南省教育廳省重點實驗室開放基金(15K108)、南華大學青年英才支持計劃(2014-002)、湖南省重點學科建設項目(湘教發(fā)[2011]76號)


Corrosion Behavior in Molten Salt of NiCoCrAlY Coating Prepared by Laser Cladding on Hastelloy N
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    摘要:

    本文采用激光熔覆同步送粉技術在Hastelloy N合金表面制備了NiCoCrAlY涂層,研究了Hastelloy N基材和含NiCoCrAlY涂層的Hastelloy N試樣在900oC LiF-NaF-KF熔鹽中的腐蝕行為。利用失重腐蝕法評估了試樣的耐熔鹽腐蝕能力,采用XRD和SEM表征了基材和涂層的物相組成、顯微組織和腐蝕形貌,并結合EDS分析了微區(qū)成分。結果表明,NiCoCrAlY涂層試樣的腐蝕速率僅為Hastelloy N基材的2/3。Hastelloy N基材表現(xiàn)為晶間腐蝕,其中Cr元素沿晶界發(fā)生選擇性脫溶腐蝕,腐蝕前由γ-Ni和Mo等物相組成,腐蝕后新析出Cr1.12Ni2.88相。NiCoCrAlY涂層表現(xiàn)為均勻腐蝕,其中Al元素充當“消耗品”由涂層均勻向外擴散,形成的腐蝕產(chǎn)物可阻礙涂層中其它元素的擴散從而保護基材,腐蝕前主要由γ-Ni、Al0.983Cr0.017、AlNi3等物相組成,腐蝕后只存在γ-Ni相。NiCoCrAlY涂層顯著提高了基材的耐熔鹽腐蝕性能。

    Abstract:

    A NiCoCrAlY coating has been prepared on Hastelloy N substrate by the powder-feeding laser cladding technique. The corrosion behaviors in molten LiF-NaF-KF salt at 900oC for 100h are studied for both the substrate and the coating. The corrosion resistance in molten FLiNaK salt is evaluated by the corrosion weight loss method, while the microanalysis on phase constitution, morphologies and compositions are carried out by XRD, SEM and EDS. The results show that, the corrosion rate of the NiCoCrAlY coating is merely two thirds that of the Hastelloy N substrate. The substrate is characterized by intergranular corrosion and the element Cr was selectively corroded along the grain boundary. The origin Hastelloy N is consisted of γ-Ni and Mo, and a new Cr1.12Ni2.88 phase is precipitated after the corrosion test. The NiCoCrAlY coating exhibits a homogeneous corrosion feature, in which the element Al diffuses outwards and the corresponding Al-rich corrosion products act as the barrier and thus protect the substrate by impeding the diffusion of other elements. The laser-cladded coating is consisted of γ-Ni, AlNi3 and Al0.983Cr0.017, and only γ-Ni retains after the corrosion test. The corrosion resistance of Hastelloy N in molten FLiNaK salt is greatly improved by the laser-cladded NiCoCrAlY coating.

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朱紅梅,陳明慧,唐忠鋒,申龍章,邱長軍. Hastelloy N合金表面激光熔覆NiCoCrAlY涂層在LiF-NaF-KF熔鹽中的腐蝕行為研究[J].稀有金屬材料與工程,2018,47(9):2767~2774.[Zhu Hongmei, Chen Minghui, Tang Zhongfeng, Shen Longzhang, Changjun Qiu. Corrosion Behavior in Molten Salt of NiCoCrAlY Coating Prepared by Laser Cladding on Hastelloy N[J]. Rare Metal Materials and Engineering,2018,47(9):2767~2774.]
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  • 收稿日期:2016-11-14
  • 最后修改日期:2017-05-06
  • 錄用日期:2017-05-15
  • 在線發(fā)布日期: 2018-11-01
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