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添加微量ZrC對鎢材料組織演變和性能的影響
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粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,粉末冶金國家重點(diǎn)實(shí)驗(yàn)室

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TG146.4+11

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國家科技攻關(guān)計(jì)劃;國家教育部博士點(diǎn)基金


Microstructure evolution and properties of tungstenreinforced by additions of ZrC
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The National Key Technologies R&D Program of China;Ph.D. Programs Foundation of the Ministry of Education of China

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    摘要:

    為了批量化制備面向等離子體用高性能鎢材料,在鎢中添加少量ZrC第二相粒子提高鎢的性能,系統(tǒng)的研究了W-ZrC材料在1150 - 2000°C常壓氫氣氣氛燒結(jié)下的致密化行為、晶粒和第二相顆粒的長大行為,并在優(yōu)化工藝下研究了ZrC含量對材料的性能和組織的影響。 結(jié)果表明,W-ZrC復(fù)合粉末在1300°C開始形成非常細(xì)小鎢晶粒, 晶粒在1600°C之前增長速率很大,在1600°C之后速率變緩。在優(yōu)化的燒結(jié)工藝下,W-ZrC材料的相對密度和拉伸強(qiáng)度最高可達(dá)到99.6%和460 MPa。ZrC以粒徑為0.1-2μm粒子均勻分散在W基體的晶界和晶粒內(nèi)部。ZrC可以有效地阻礙W晶界的遷移,有效的將鎢的晶粒由100μm細(xì)化至30μm左右。ZrC改變了鎢材料的斷裂模式,并提高強(qiáng)度和韌性。

    Abstract:

    In order to prepare high performance tungsten used as plasma face material, trace amount of ZrC was added to tungsten, and the densification behavior, properties and microstructure evolution of W-ZrC composites sintered at temperatures in the rang 1150 - 2000°C with flowing hydrogen atmosphere were investigated systematically. Results show that W-ZrC composite powders begin to form fine tungsten grains at 1300°C. The growth rate of grains is high at temperatures below 1600°C, and then slows down. The maximum relative density and tensile strength are 99.6% and 460MPa respectively under the optimum sintering process. ZrC particles are uniformly dispersed at grain boundaries and in grains interior with particle size from 0.1μm to 2 μm. Minor ZrC can effectively prevent the migration of grain boundaries and refine grain sizes from 100 μm of pure tungsten to 30 μm of W-ZrC composites. Minor ZrC can change the fracture mode and improve the strength and toughness of tungsten.

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李鵬飛,范景蓮,韓勇,章曼,成會朝,田家敏.添加微量ZrC對鎢材料組織演變和性能的影響[J].稀有金屬材料與工程,2018,47(6):1695~1699.[lipengfei, fanjinglian, hanyong, zhangman, chenghuichao, tianjiamin. Microstructure evolution and properties of tungstenreinforced by additions of ZrC[J]. Rare Metal Materials and Engineering,2018,47(6):1695~1699.]
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  • 收稿日期:2016-10-17
  • 最后修改日期:2017-01-10
  • 錄用日期:2017-02-21
  • 在線發(fā)布日期: 2018-09-06
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