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AZ91鎂合金表面微弧氧化與磁控濺射鍍銅復(fù)合處理層的微觀組織與性能
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西安理工大學(xué)材料科學(xué)與工程學(xué)院,西安理工大學(xué)材料科學(xué)與工程學(xué)院,西安理工大學(xué)材料科學(xué)與工程學(xué)院,西安理工大學(xué)材料科學(xué)與工程學(xué)院

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TG174.4; TG179

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陜西省自然科學(xué)基礎(chǔ)研究計(jì)劃(重點(diǎn)項(xiàng)目) (項(xiàng)目號(hào)2016JZ018)


Microstructure and Properties of Duplex Coating on AZ91 Magnesium Alloy Combined with MAO and Magnetic Sputtering Copper
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Xi''an University of Technology,,,

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    摘要:

    采用微弧氧化技術(shù)在AZ91鎂合金表面制備陶瓷涂層,然后在該涂層表面通過磁控濺射鍍銅技術(shù)制備復(fù)合膜層。研究了微弧氧化陶瓷層和復(fù)合膜層的表面物相組成、表面粗糙度、表面及截面形貌、表面潤濕性及電化學(xué)性能。結(jié)果表明:AZ91鎂合金經(jīng)微弧氧化處理后由于微弧氧化陶瓷層呈微納粗糙多孔結(jié)構(gòu),表現(xiàn)為親水特性,其物相由MgO、Mg及Mg2SiO4組成;而微弧氧化陶瓷層經(jīng)磁控濺射鍍銅處理后表面獲得較為致密的具有疏水特性的銅層,表面粗糙度降低;四探針測(cè)試結(jié)果說明復(fù)合膜層的方阻為16.2mΩ?□-1,導(dǎo)電性良好;動(dòng)電位極化曲線測(cè)試結(jié)果說明復(fù)合膜層與基體鎂合金相比,其腐蝕電流密度降低10%,腐蝕電位提高了0.36V,腐蝕極化電阻提高約80倍;與微弧氧化陶瓷層相比,復(fù)合膜層的腐蝕電位提高了0.24V,但其腐蝕電流密度和腐蝕極化電阻有所下降。研究結(jié)果表明,微弧氧化與磁控濺射鍍銅相結(jié)合的復(fù)合處理技術(shù)可在不降低鎂合金陶瓷層耐蝕性的基礎(chǔ)上顯著提高其表面的導(dǎo)電性能。

    Abstract:

    Porous ceramic coating were prepared on AZ91 magnesium alloy by micro-arc oxidation (MAO), and the duplex coating were prepared by magnetic sputtering copper. The surface phase?composition, surface roughness, surface and cross-sectional morphology, surface wettability, and electrochemical characteristics of MAO and duplex coatings were studied. The results indicate that the surface of AZ91 magnesium alloy treated by MAO shows hydrophilic due to its micro-nano coarse porous structure, and its phase?consists of MgO, Mg and Mg2SiO4. However, the surface of MAO coating turns into relatively compact copper with hydrophobic property after magnetic sputtering copper, at the same time the surface roughness decreases a little. Four-point probe measurement indicates that the duplex coating exhibits well electrical conductivity,the sheet resistance is 16.2mΩ?□-1. Meanwhile, potentiodynamic polarization curves reveal that the corrosion current density of duplex coating reduces to 10%, and the corrosion?potential increases 0.36V, while the polarization resistance increases around 80?times compared with bare magnesium alloy. Compared with the MAO coating, the corrosion?potential of the duplex coating increases 0.24V, suggesting that the corrosion trend decreases. Nevertheless, the corrosion current density and polarization resistance of the duplex coating all decrease to some extent. These?survey?results?indicate that the duplex treatment by MAO and magnetic sputtering copper on surface of the magnesium alloy improve its electrical conductivity greatly?without?losing corrosion resistance of magnesium alloy.

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王志虎,白力靜,王愛玲,張國君. AZ91鎂合金表面微弧氧化與磁控濺射鍍銅復(fù)合處理層的微觀組織與性能[J].稀有金屬材料與工程,2018,47(8):2561~2566.[Wang Zhihu, Bai Lijing, Wang Ailing, Zhang Guojun. Microstructure and Properties of Duplex Coating on AZ91 Magnesium Alloy Combined with MAO and Magnetic Sputtering Copper[J]. Rare Metal Materials and Engineering,2018,47(8):2561~2566.]
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  • 收稿日期:2016-09-14
  • 最后修改日期:2017-04-09
  • 錄用日期:2017-04-13
  • 在線發(fā)布日期: 2018-10-17
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