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SiC對(duì)Ni-W合金耐蝕耐磨性能的強(qiáng)化作用
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河海大學(xué) 力學(xué)與材料學(xué)院 江蘇 南京,河海大學(xué) 力學(xué)與材料學(xué)院 江蘇 南京,河海大學(xué) 力學(xué)與材料學(xué)院 江蘇 南京,河海大學(xué) 機(jī)電工程學(xué)院 江蘇 常州

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0646.5; TQ153.2

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)51301061, 51679076),中央高?;緲I(yè)務(wù)費(fèi)項(xiàng)目資助(項(xiàng)目號(hào)2013B32614)


Effect of SiC on the Corrosion and Wear Resistance of the Ni-W Alloys
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College of Mechanics and Materials,Hohai University Nanjing,College of Mechanics and Materials,Hohai University Nanjing,College of Mechanics and Materials,Hohai University Nanjing,College of Mechanical and Electrical Engineering,Hohai University

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    摘要:

    為提高嚴(yán)苛海洋環(huán)境下金屬機(jī)件的服役性能,本文通過(guò)電沉積方法制備了Ni-W和Ni-W/SiC復(fù)合鍍層。利用掃描電子顯微鏡(SEM)、能譜分析(EDS)和X射線衍射(XRD)等技術(shù)研究了SiC對(duì)Ni-W合金微觀結(jié)構(gòu)和性能的影響,采用電化學(xué)方法研究了復(fù)合鍍層在3.5% NaCl溶液中的耐蝕性能,以探討其海水綜合防護(hù)性能。研究表明,經(jīng)表面處理的SiC可誘導(dǎo)形核促進(jìn)晶體生長(zhǎng),使Ni-W合金晶粒變細(xì),鍍層完整致密。SiC納米顆粒均勻分布在Ni-W/SiC中,可有效提高鍍層硬度及耐磨性,同時(shí)Ni-W/SiC也具有比Ni-W合金更好的耐蝕性能,在多因素交互作用的海洋環(huán)境中將具有更長(zhǎng)的防護(hù)壽命,具有良好的應(yīng)用前景

    Abstract:

    To improve the service performance of metal parts in harsh marine environment, the effects of SiC on the corrosion and wear resistance of the Ni-W Alloys were investigated by scanning electron microscopy (SEM), energy spectrum analysis (EDS) and X ray diffraction (XRD). The influences of SiC nanoparticles on Ni-W composite electrodeposition process and the electrochemical corrosion properties of Ni-W/SiC composite coatings were studied by EIS and Tafel methods. The results show that SiC which pretreated were uniformly dispersed in compact Ni-W/SiC coating which can effectively improve the hardness and wear resistance at the same time. The addition of W6+ refine the grain size of the Ni coating, reduce the porosity, transform some structure to amorphous and improve the corrosion resistance. SiC nano particles can promote the nucleation and growth of Ni-W alloy and improve the hardness of the alloys. Compared with Ni-W alloys, with the wear resistance increased and porosity decreased, Ni-W/SiC alloys have excellent corrosion resistance and wear resistance. Ni-W/SiC alloys also have better abrasion and corrosion resistance than Ni-W alloy, and can provide comprehensive service performance for marine parts under the influence of multifactor interaction in seawater environment. It has a good application prospect in the field of marine engineering protection.

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引用本文

李保松,張文,環(huán)宇星,張薇薇. SiC對(duì)Ni-W合金耐蝕耐磨性能的強(qiáng)化作用[J].稀有金屬材料與工程,2017,46(10):3129~3134.[Li Baosong, Zhang Wen, Huan Yuxing, Zhang Weiwei. Effect of SiC on the Corrosion and Wear Resistance of the Ni-W Alloys[J]. Rare Metal Materials and Engineering,2017,46(10):3129~3134.]
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  • 收稿日期:2016-08-19
  • 最后修改日期:2016-11-10
  • 錄用日期:2016-12-02
  • 在線發(fā)布日期: 2017-12-01
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