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超音速等離子噴涂制備金屬陶瓷涂層的抗沖蝕性能
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國(guó)家自然科學(xué)基金資助(51202211,51202187);中國(guó)博士后科學(xué)基金(2014M562404)


Erosion Resistance of Cermet Coatings Deposited by Supersonic Atmospheric Plasma Spraying
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    摘要:

    本文通過(guò)國(guó)產(chǎn)高效能超音速等離子噴涂(SAPS)制備WC-Co及WC-NiCr金屬陶瓷涂層,對(duì)比研究?jī)煞N涂層的抗沖蝕性能及在熱腐蝕條件下的結(jié)構(gòu)及性能演變,結(jié)果表明:兩種涂層在噴涂過(guò)程中均會(huì)發(fā)生一定程度的脫碳,表現(xiàn)為 W2C相的形成。同時(shí)在WC-Co涂層中有少量的 Co3W3C和Co6W6C相生成,且該涂層在熱腐蝕后表層的WC相出現(xiàn)了分解與氧化,形成了 W3C、W6C2.54等脫碳相與CoWO4、WO3等氧化物相。在普通沖蝕條件下,WC-Co涂層的抗沖蝕性能更為優(yōu)異,但熱腐蝕會(huì)極大降低WC-Co涂層的抗沖蝕性能;與之相反,WC-NiCr涂層中的 NiCr相在熱腐蝕環(huán)境下生成的 Cr2O3可以有效阻擋涂層內(nèi)部與外部之間的物質(zhì)擴(kuò)散,從而降低了熱腐蝕對(duì)涂層結(jié)構(gòu)的破壞,在熱腐蝕條件下表現(xiàn)出了優(yōu)良的抗沖蝕性能。

    Abstract:

    In this work, WC-Co and WC-NiCr cermet coatings were deposited by high-efficiency supersonic atmospheric plasma spraying. The erosion resistance of both coatings was comparatively studied in normal or hot corrosion condition. Experimental results suggested that the decarburization happened during the spray of WC-Co or WC-NiCr powders, which led to the formation of W2C. Meanwhile, Co3W3C and Co6W6C were also found in WC-Co coating. Some new phases, such as W3C, W6C2.54, CoWO4 and WO3, were observed in WC-Co coating due to the decomposition and oxidation of WC during hot corrosion. WC-Co coating showed a higher erosion resistance than WC-NiCr coating, however, the erosion resistance of former significantly decreased after hot corrosion. On the contrary, the Cr2O3 that formed during hot corrosion can effectively protect WC from oxidation and thus improve the erosion resistance of WC-NiCr coating.

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.超音速等離子噴涂制備金屬陶瓷涂層的抗沖蝕性能[J].稀有金屬材料與工程,2018,47(6):1884~1889.[. Erosion Resistance of Cermet Coatings Deposited by Supersonic Atmospheric Plasma Spraying[J]. Rare Metal Materials and Engineering,2018,47(6):1884~1889.]
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  • 收稿日期:2016-07-27
  • 最后修改日期:2017-03-07
  • 錄用日期:2017-03-15
  • 在線(xiàn)發(fā)布日期: 2018-09-06
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