2-MoSi2雙層抗燒蝕涂層。借助XRD、SEM、EDS等分析手段對涂層的組織結(jié)構(gòu)進(jìn)行研究;基于氧丙烯焰燒蝕試驗考察ZrB2-MoSi2/mullite復(fù)合涂層對C/C復(fù)合材料高溫耐燒蝕性能的影響。結(jié)果表明,在1700 °C和1800 °C的氧丙烯焰下燒蝕60 s,ZrB2-MoSi2/mullite涂層試樣的質(zhì)量燒蝕率分別為3.49×10-3 g/s與3.77×10-3 g/s。其與單層ZrB2-MoSi2涂層試樣相比,ZrB2-MoSi2/mullite涂層試樣展現(xiàn)了出色的抗燒蝕性能。燒蝕過程中形成的硅酸鹽玻璃可以作為熱障層而減少氧氣的進(jìn)一步滲透,并且還具有自我封填缺陷的能力,使ZrB2-MoSi2/mullite涂層表現(xiàn)較好的抗燒蝕性。"/>

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C/C復(fù)合材料大氣等離子噴涂mullite/ZrB2-MoSi2涂層抗燒蝕性能
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華南理工大學(xué)材料科學(xué)與工程學(xué)院,廣東省新材料研究所,廣東省新材料研究所,廣東省新材料研究所,華南理工大學(xué)材料科學(xué)與工程學(xué)院,廣東省新材料研究所

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TB332

基金項目:

廣東省自然科技基金(No. 2016A030312015);廣東省科學(xué)計劃項目 (No. 2013B050800031,No.2014B050502008 and No.2015B070701024)


Ablation Resistance of APS Sprayed Mullite/ZrB2-MoSi2 Coating for Carbon/Carbon Composites
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School of Materials Science and Engineering,South China University of Technology,Guangdong Institute of New Materials,National Engineering Laboratory for Modern Materials surface Engineering Technology,Guangdong Provincial Key Lab for Modern Materials Surface Engineering Technology,Guangdong Institute of New Materials,National Engineering Laboratory for Modern Materials surface Engineering Technology,Guangdong Provincial Key Lab for Modern Materials Surface Engineering Technology,Guangdong Institute of New Materials,National Engineering Laboratory for Modern Materials surface Engineering Technology,Guangdong Provincial Key Lab for Modern Materials Surface Engineering Technology,School of Materials Science and Engineering,South China University of Technology,Guangdong Institute of New Materials,National Engineering Laboratory for Modern Materials surface Engineering Technology,Guangdong Provincial Key Lab for Modern Materials Surface Engineering Technology

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    摘要:

    采用大氣等離子噴涂技術(shù)(APS)在C/C復(fù)合材料表面制備了mullite/ZrB2-MoSi2雙層抗燒蝕涂層。借助XRD、SEM、EDS等分析手段對涂層的組織結(jié)構(gòu)進(jìn)行研究;基于氧丙烯焰燒蝕試驗考察ZrB2-MoSi2/mullite復(fù)合涂層對C/C復(fù)合材料高溫耐燒蝕性能的影響。結(jié)果表明,在1700 °C和1800 °C的氧丙烯焰下燒蝕60 s,ZrB2-MoSi2/mullite涂層試樣的質(zhì)量燒蝕率分別為3.49×10-3 g/s與3.77×10-3 g/s。其與單層ZrB2-MoSi2涂層試樣相比,ZrB2-MoSi2/mullite涂層試樣展現(xiàn)了出色的抗燒蝕性能。燒蝕過程中形成的硅酸鹽玻璃可以作為熱障層而減少氧氣的進(jìn)一步滲透,并且還具有自我封填缺陷的能力,使ZrB2-MoSi2/mullite涂層表現(xiàn)較好的抗燒蝕性。

    Abstract:

    Mullite/ZrB2-MoSi2 coating was deposited on carbon/carbon(C/C) composites to protect against ablation by atmospheric plasma spraying (APS). The microstructure and morphology of the coating were characterized by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The ablation resistance of the coating was investigated at different temperatures with oxypropylene torch. The mass ablation rates of the Mullite/ZrB2-MoSi2 coated C/C composites were 3.49×10-3 g/s and 3.77×10-3 g/s after ablation at 1700 °C and 1800 °C for 60 s respectively, which exhibited good ablation resistance compared with the single-layer ZrB2-MoSi2 coated. The increase of ablation resistance can be attributed to the formation of a silicates glass film, which acted as thermal barrier and self-sealed the defects of the coatings.

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韓偉,劉敏,鄧春明,劉學(xué)璋,曾德長,周克崧. C/C復(fù)合材料大氣等離子噴涂mullite/ZrB2-MoSi2涂層抗燒蝕性能[J].稀有金屬材料與工程,2018,47(4):1043~1048.[Han Wei, Liu Min, Deng Chunming, Liu Xuezhang, Zeng Dechang, Zhou Kesong. Ablation Resistance of APS Sprayed Mullite/ZrB2-MoSi2 Coating for Carbon/Carbon Composites[J]. Rare Metal Materials and Engineering,2018,47(4):1043~1048.]
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  • 收稿日期:2016-07-21
  • 最后修改日期:2018-04-19
  • 錄用日期:2016-09-14
  • 在線發(fā)布日期: 2018-05-31
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