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熱處理對HA/Mg-Zn-Ca生物復合材料顯微組織及性能的影響
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天津理工大學材料科學與工程學院,天津理工大學材料科學與工程學院,天津理工大學材料科學與工程學院,天津理工大學材料科學與工程學院

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國家自然科學基金資助(51271131),天津市科技支撐重點項目(15ZCZDSY00920)及天津市科技特派員項目


Effects of heat treatment on microstructures and properties of HA/Mg-Zn-Ca biocomposite
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School of Materials Science and Engineering,Tianjin University of technology,School of Materials Science and Engineering,Tianjin University of technology,School of Materials Science and Engineering,Tianjin University of technology,School of Materials Science and Engineering,Tianjin University of technology

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    摘要:

    鎂及鎂合金具有良好的生物相容性、與人骨相近的力學性能及生物可降解性。通過在鎂合金基礎上添加生物陶瓷顆粒可以調(diào)控復合材料的力學及腐蝕降解性能,滿足不同服役情況的需求。本文采用剪切攪拌鑄造結合熱擠壓工藝制備了1HA/Mg-3Zn-0.2Ca(wt.%)復合材料,研究了固溶及時效處理對擠壓態(tài)1HA/Mg-3Zn-0.2Ca復合材料顯微組織、力學性能及電化學腐蝕行為的影響。結果表明:擠壓態(tài)復合材料經(jīng)T4固溶處理后,第二相數(shù)量減少,晶粒尺寸增大,屈服強度降低,但延伸率和耐蝕性能有所提高。固溶超過3h后,耐蝕能力由于晶粒尺寸過分長大又出現(xiàn)下降;固溶后時效處理(T6),復合材料屈服強度提高,耐蝕性變化不大。因此,對擠壓態(tài)HA/Mg-Zn-Ca復合材料進行適當?shù)墓倘芗皶r效處理可以提高復合材料的耐蝕性及延伸率。

    Abstract:

    Magnesium and magnesium alloys have attracted increasing attention as implant materials due to their suitable mechanical properties with bones, good biocompatibility and biodegradability in physiological environment. The addition of bioceramic particles into magnesium alloy can adjust mechanical properties as well as the corrosion properties to meet the requirements service performance. In this paper, 1HA/Mg-3Zn-0.2Ca composities were fabricated by means of melt high shearing technology combined with following hot extrusion. Effects of heat treatment on microstructures, mechanical and corrosion resistance properties were investigated. The results indicated that after solid solution treatment (T4 treatment), the amounts of secondary phases in 1HA/Mg-3Zn-0.2Ca composite decreases, grain size became larger, yield strength decreased, the elongation and the corrosion resistance increased. However, the corrosion resistance show a decreasing trend as the solid solution treatment time exceeded 3h , which was attributed to grain size is overlarge. Aging treatment after solid solution, the yield strength increased and the corrosion resistance was not changed obviously. Hence, the as-extruded 1HA/Mg-3Zn-0.2Ca composite can be improved the corrosion resistance and elongation by suitable solid solution and aging heat treatment.

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姜婭玲,劉德寶,楊敏,趙越.熱處理對HA/Mg-Zn-Ca生物復合材料顯微組織及性能的影響[J].稀有金屬材料與工程,2017,46(10):3111~3116.[Jiang Yaling, Liu Debao, Yang Min, Zhao Yue. Effects of heat treatment on microstructures and properties of HA/Mg-Zn-Ca biocomposite[J]. Rare Metal Materials and Engineering,2017,46(10):3111~3116.]
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  • 收稿日期:2016-07-12
  • 最后修改日期:2016-11-17
  • 錄用日期:2016-12-02
  • 在線發(fā)布日期: 2017-12-01
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