2Ni 和Ti2(Ni,Pd)等,起到固溶強(qiáng)化和沉淀強(qiáng)化作用,改善高溫記憶合金高溫記憶性能。在一定應(yīng)力條件下訓(xùn)練處理在基體形成具有特定應(yīng)力場(chǎng)位錯(cuò)組態(tài)易于誘發(fā)擇優(yōu)取向的馬氏體變體形核,從而提高高溫單程和雙程記憶性能和功能尺寸穩(wěn)定性。"/>

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NiTi基高溫記憶合金相變行為與組織性能研究
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有研億金新材料有限公司,有研醫(yī)療器械(北京)有限公司,有研醫(yī)療器械(北京)有限公司,有研億金新材料有限公司,有研醫(yī)療器械(北京)有限公司,有研醫(yī)療器械(北京)有限公司,有研億金新材料有限公司,有研億金新材料有限公司,有研億金新材料有限公司

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2015年工業(yè)轉(zhuǎn)型升級(jí)強(qiáng)基工程資金資助(項(xiàng)目名稱:高性能形狀記憶合金及智能材料,項(xiàng)目編號(hào)TC150B5C0/03)


Study on the phase transformation behaviour, microstructure and property of NiTi based high temperature shape memory alloys
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Grikin Advanced Materials Co,Ltd,,GRIMED Medical Beijing Co,Ltd,Grikin Advanced Materials Co,Ltd,GRIMED Medical Beijing Co,Ltd,GRIMED Medical Beijing Co,Ltd,Grikin Advanced Materials Co,Ltd,Grikin Advanced Materials Co,Ltd,Grikin Advanced Materials Co,Ltd

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    摘要:

    本文總結(jié)了近年來(lái)國(guó)內(nèi)外Ni-Ti-Pd和Ni-Ti-Pt高溫鎳鈦形狀記憶合金研究進(jìn)展,分析了化學(xué)成分、熱機(jī)械處理和訓(xùn)練工藝等對(duì)高溫記憶合金的馬氏體相變行為、高溫單程和雙程記憶性能和循環(huán)使用性能穩(wěn)定性等方面的影響。研究結(jié)果表明,Ni-Ti-Pd和Ni-Ti-Pt高溫鎳鈦形狀記憶合金的相變溫度、滯后寬度、高溫馬氏體變形與蠕變行為、高溫循環(huán)特性等受顯微組織影響顯著。通過(guò)采取Sc、B、Cu等元素合金化、固溶和時(shí)效、冷軋退火處理,有利于細(xì)化晶粒,在基體析出細(xì)小彌散沉淀相,如Ti2Ni 和Ti2(Ni,Pd)等,起到固溶強(qiáng)化和沉淀強(qiáng)化作用,改善高溫記憶合金高溫記憶性能。在一定應(yīng)力條件下訓(xùn)練處理在基體形成具有特定應(yīng)力場(chǎng)位錯(cuò)組態(tài)易于誘發(fā)擇優(yōu)取向的馬氏體變體形核,從而提高高溫單程和雙程記憶性能和功能尺寸穩(wěn)定性。

    Abstract:

    Research progress on the Ni-Ti-Pd and Ni-Ti-Pt high temperature shape memory alloys at home and abroad in recent years were reviewed, and the effect of chemical composition, thermal mechanical treatment and the training process on martensitic transformation, high temperature performance of one-way and two-way shape memory effect, and functional stability during repeated thermomechanical cycling of high temperature shape memory alloy were analyzed.The results show that the transformation temperature, the width of transformation hysteresis, high temperature martensitic transformation induced plasticity, creep behaviour, and high temperature thermal cycling properties, were significantly affected by the microstructures.The refinement of grain structure were achieved by the addition of Sc, Cu, or B elements, and cold rolling followed by annealling treatments, and the fine dispersed precipitaties of Ti2Ni and Ti2(Ni,Pd) distributed in the matrix were produced by solid solution and aging, and these microstructures were beneficial to the improvement of the high temperature shape memory properties, by the effect of solid solution hardening and precipitation hardening.The preferentially oriented martensite variants, nucleated on the dislocation arrays with the specific stress field obtained during the training under a constant stress, were found to improve the one-way and two-way shape memory properties, and improve the stability of the functional properties and size of the high temperature shape memory alloys.

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袁志山,吝德智,崔躍,馮昭偉,李君濤,尚再艷,朱明,熊曉東,王興權(quán). NiTi基高溫記憶合金相變行為與組織性能研究[J].稀有金屬材料與工程,2018,47(7):2269~2274.[Zhishan Yuan, Dezhi Lin, Yue Cui, Zhaowei Feng, Juntao Li, Zaiyan Shang, Ming Zhu, Xiaodong Xiong, Xingquan Wang. Study on the phase transformation behaviour, microstructure and property of NiTi based high temperature shape memory alloys[J]. Rare Metal Materials and Engineering,2018,47(7):2269~2274.]
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  • 收稿日期:2016-07-12
  • 最后修改日期:2016-10-20
  • 錄用日期:2016-11-11
  • 在線發(fā)布日期: 2018-10-10
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