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Ni35摻雜高碳鉻鐵粉激光熔覆涂層組織性能研究
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遼寧工程技術大學 材料科學與工程學院,遼寧工程技術大學 材料科學與工程學院

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遼寧省自然科學資助(No.:2014020155);遼寧省科學事業(yè)公益研究基金(No:2014003007)


Study on Microstructure and Properties of Ni35 with High Carbon Ferrochrome Powders by Laser Cladding
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College of Material Science and Engineering,Liaoning Technical University,Fuxin,College of Material Science and Engineering,Liaoning Technical University,Fuxin

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    摘要:

    Ni35粉末摻雜不同質(zhì)量分數(shù)(含量分別為0%、25%、50%、75%、100%)高碳鉻鐵粉末,在27SiMn鋼表面進行激光熔覆制備復合涂層。采用OM、SEM、EDS及XRD等表征手段,表征熔覆層顯微組織及物相結構;利用硬度計、磨粒磨損機及電化學站等儀器,表征熔覆層力學及腐蝕性能。結果表明:未摻雜時,熔覆層物相主要有γ-Ni、FeNi3及Cr2Ni3,含量50%時,熔覆層物相有α-Cr和(Cr, Fe)7C3生成,同時Cr2Ni3相消失;隨著含量增加,熔覆層中部板條狀組織含量增多且形貌變得粗大;含量50%時,熔覆層上部花瓣狀組織及中部板條狀組織均出現(xiàn)Cr元素富集現(xiàn)象,淺灰色組織為γ-Ni;隨著含量增加,熔覆層顯微硬度呈上升趨勢,磨損率呈下降趨勢;含量25%時,稀釋率最大,為20.80%;含量50%時,熔覆層耐蝕性最佳,腐蝕電流密度最小,為0.39 μA/cm2。

    Abstract:

    The Ni35 powder with different mass fraction (the contents are 0%, 25%, 50%, 75% and 100% respectively) of high carbon ferrochrome powder was prepared on the surface of 27SiMn steel using laser cladding technology. The microstructure and the phase of the laser cladding layers were studied by the means of OM, SEM, EDS and XRD. Using micro-hardness tester, abrasive wear machine and electrochemical corrosion tester, the mechanical and corrosion properties of the laser cladding layers were studied. The experimental results show that: the phases of the cladding layers without high carbon ferrochrome are γ-Ni、FeNi3 and Cr2Ni3. When the content is 50%, the α-Cr and (Cr, Fe)7C3 are produced while the Cr2Ni3 disappears. With increasing the content of high carbon ferrochrome, the lath microstructures increase and coarsen constantly. When the content is 50%, Cr element enrichment happens in the petal-looking microstructure of the upper cladding layer and the lath microstructure of the middle cladding layer, and the light gray microstructure is γ-Ni. And with the content increasing, the micro-hardness increase while the wear rate reduce. When the content is 25%, the maximum dilution rate is 20.80% and when the content is 50%, the cladding layers have the best corrosion resistance, and the corrosion current density is the least, which is 0.39 μA/cm2.

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李剛,張井波. Ni35摻雜高碳鉻鐵粉激光熔覆涂層組織性能研究[J].稀有金屬材料與工程,2018,47(6):1830~1835.[Li Gang, Zhang Jingbo. Study on Microstructure and Properties of Ni35 with High Carbon Ferrochrome Powders by Laser Cladding[J]. Rare Metal Materials and Engineering,2018,47(6):1830~1835.]
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  • 收稿日期:2016-05-09
  • 最后修改日期:2017-09-27
  • 錄用日期:2017-11-01
  • 在線發(fā)布日期: 2018-09-06
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