2;擴(kuò)散法;臨界電流密度;磁通釘扎"/> 3的MgB2超導(dǎo)塊材。論文研究了不同的熱處理?xiàng)l件對(duì)MgB2塊材的超導(dǎo)轉(zhuǎn)變溫度(Tc)和臨界電流密度(Jc)性能的影響。采用最佳熱處理?xiàng)l件制備的MgB2超導(dǎo)體Tc和Jc分別達(dá)到了38.1K和0.53MA/cm2(10K,自場(chǎng))。為了改進(jìn)鎂擴(kuò)散法MgB2超導(dǎo)體中弱的高場(chǎng)磁通釘扎性能,本文還研究了nano-Pr6O11和C摻雜對(duì)MgB2超導(dǎo)體的臨界電流密度和不可逆場(chǎng)(Hirr)的影響。結(jié)果表明C摻雜的MgB2超導(dǎo)體臨界電流密度在10K,6T下達(dá)到了104A/cm2,該結(jié)果比未摻雜MgB2超導(dǎo)體在同樣條件下性能提高了兩個(gè)量級(jí),甚至比固態(tài)反應(yīng)法制備的nano-C摻雜MgB2超導(dǎo)體性能更好。利用該方法制備的nano-Pr6O11摻雜的MgB2超導(dǎo)體在10K,2T下也比未摻雜樣品Jc提高達(dá)9.4倍。根據(jù)大量的實(shí)驗(yàn)結(jié)果和理論分析我們提出基于改進(jìn)型鎂擴(kuò)散法和化學(xué)摻雜,包括納米粒子和C摻雜,很有可能是一種制備高性能MgB2超導(dǎo)體非常有效的途徑。"/>

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改進(jìn)型鎂擴(kuò)散法制備高臨界電流密度MgB2超導(dǎo)體性能研究
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西部超導(dǎo)材料科技股份有限公司,西部超導(dǎo)材料科技股份有限公司,西部超導(dǎo)材料科技股份有限公司,西部超導(dǎo)材料科技股份有限公司,西部超導(dǎo)材料科技股份有限公司,西北有色金屬研究院,西部超導(dǎo)材料科技股份有限公司

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國(guó)家高技術(shù)研究發(fā)展計(jì)劃(863計(jì)劃)


High critical current density on MgB2 bulks synthesized by an improved Mg-diffusion method
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Westen Superconducting Technologies Co.,Ltd.,,,,,,

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    本文采用一種改進(jìn)型鎂擴(kuò)散法成功制備出密度達(dá)到1.95g/cm3的MgB2超導(dǎo)塊材。論文研究了不同的熱處理?xiàng)l件對(duì)MgB2塊材的超導(dǎo)轉(zhuǎn)變溫度(Tc)和臨界電流密度(Jc)性能的影響。采用最佳熱處理?xiàng)l件制備的MgB2超導(dǎo)體Tc和Jc分別達(dá)到了38.1K和0.53MA/cm2(10K,自場(chǎng))。為了改進(jìn)鎂擴(kuò)散法MgB2超導(dǎo)體中弱的高場(chǎng)磁通釘扎性能,本文還研究了nano-Pr6O11和C摻雜對(duì)MgB2超導(dǎo)體的臨界電流密度和不可逆場(chǎng)(Hirr)的影響。結(jié)果表明C摻雜的MgB2超導(dǎo)體臨界電流密度在10K,6T下達(dá)到了104A/cm2,該結(jié)果比未摻雜MgB2超導(dǎo)體在同樣條件下性能提高了兩個(gè)量級(jí),甚至比固態(tài)反應(yīng)法制備的nano-C摻雜MgB2超導(dǎo)體性能更好。利用該方法制備的nano-Pr6O11摻雜的MgB2超導(dǎo)體在10K,2T下也比未摻雜樣品Jc提高達(dá)9.4倍。根據(jù)大量的實(shí)驗(yàn)結(jié)果和理論分析我們提出基于改進(jìn)型鎂擴(kuò)散法和化學(xué)摻雜,包括納米粒子和C摻雜,很有可能是一種制備高性能MgB2超導(dǎo)體非常有效的途徑。

    Abstract:

    MgB2 bulks with a density, 1.95g/cm3, have been successfully prepared by an improved Mg-diffusion method. The effects of different heat treatment conditions on superconducting transitions temperature, Tc and critical current density, Jc of MgB2 have been discussed. The MgB2 synthesized by optimal heat treatment conditions has the Tc, 38.1K and Jc at 10K, self-field, 0.53MA/cm2. In order to improve poor high field properties in diffusion method, nano-Pr6O11 and C doping effects on Jc and the irreversible field, Hirr of MgB2 have also been studied. The results show that at 10K and 6T the Jc for 15 at.% C-doped MgB2 reaches 104 A/cm2, which is almost two orders of magnitude higher than the undoped one, and better than the nano-C doped MgB2 prepared by solid-state reaction. For the nano-Pr6O11-doped MgB2, the Jc also increases by a factor of 9.4 than the pure sample at 10K and 2T. According to a great of experimental results and theoretic analyses, we propose that the combination of the improved Mg-diffusion method and chemical doing, nanoparticles or C doping, may be an efficient approach to make the MgB2 have excellent Jc and Hirr capability in whole magnetic field.

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侯艷榮,潘熙鋒,閆果,王大友,崔利軍,馮建情,馮勇.改進(jìn)型鎂擴(kuò)散法制備高臨界電流密度MgB2超導(dǎo)體性能研究[J].稀有金屬材料與工程,2018,47(5):1406~1410.[houyanrong, panxifeng, yan-guo, wangdayou, cuilijun, fengjianqing, fengyong. High critical current density on MgB2 bulks synthesized by an improved Mg-diffusion method[J]. Rare Metal Materials and Engineering,2018,47(5):1406~1410.]
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  • 收稿日期:2016-05-05
  • 最后修改日期:2016-08-01
  • 錄用日期:2016-08-18
  • 在線發(fā)布日期: 2018-06-08
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