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NiCr涂層結構對Nb-1Zr合金抗氧化性能的影響
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西安建筑科技大學,西北有色金屬研究院

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科技部中烏國際合作項目,2014DFR50450;國家重點基礎研究發(fā)展計劃項目,2012CB625100


Effects of NiCr coatings’ microstructure on oxidation resistance of Nb-1Zr alloys
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National International Science and Technology Corporation (2014DFR50450), National Basic Research Program of China (2012CB625100)

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    摘要:

    為提高Nb-1Zr合金基體在600℃大氣環(huán)境下的抗氧化性能,本文采用等離子增強電弧離子鍍技術在Nb-1Zr合金表面低于300℃條件下實現(xiàn)不同復合結構的NiCr涂層。利用恒溫氧化表征了涂層在600℃、500小時大氣環(huán)境下的抗氧化性能,揭示了不同復合結構涂層失效以及抗氧化機理。結果表明,單一NiCr涂層中存在的大量“微孔“結構缺陷相互連通構成了氧元素進入基體的擴散通道,界面處基體首先發(fā)生氧化,生成以Nb2O5為主的粉末狀氧化產(chǎn)物。隨著氧化時間的延長,氧化產(chǎn)物逐漸增多,體積逐漸膨脹,造成表面鼓泡直至破裂失效。采用NiCr多層復合結構能夠顯著降低涂層中形成“貫穿孔“的幾率,但并未改變涂層的失效方式。而基體與NiCr層之間引入Cr過渡層,能夠在界面處與擴散進入的氧首先反應生成致密的Cr2O3層,阻礙氧向基體的進一步擴散,且隨著氧化時間的延長,涂層中的Cr向表面的擴散使得其表面相應形成一層致密的Cr2O3層,雙層致密氧化膜的形成確保了基體抗氧化性能的提高。研究結果顯示,Cr/NiCr多層復合結構涂層能夠使Nb-1Zr合金在600℃大氣環(huán)境下的抗氧化時間延長至500小時,氧化增重率僅有0.08 g/m2.h。

    Abstract:

    In order to improve the Nb-1Zr alloys’ oxidation resistance, a series of NiCr coatings with different composite structure were deposited on Nb-1Zr alloys by Plasma enhanced ion plating bellow 300℃. By means of isothermal oxidation, NiCr coatings’ oxidation resistance property was studied in detail. The mechanism of invalidation and oxidation resistance of NiCr coating with different microstructure was revealed. The results showed that a channel for oxygen diffusion could be formed by the micro holes communicating with each other in the single layer NiCr. So the Nb-1Zr matrix near the interface would be oxidized firstly and Nb2O5 based oxide powder was generated which gradually was increased along with the oxidation time, causing the breakage of coating. That “through holes” can be significantly reduced by NiCr multilayer composite structure, but the coatings’ failure mode was not changed. By introducing the Cr interlayer, the diffusion of oxygen would easily be absorbed and a dense Cr2O3 layer was formed which can discourage the further diffusion of oxygen into the Nb matrix. And also a dense Cr2O3 layer could also be formed on the surface of Cr/NiCr multilayer coating by diffusion of Cr. As a result, the Nb-1Zr alloy’s oxidation resistance could be improved. After oxidizing at 600℃ for 500 hours, The weight gain rate of Nb-1Zr alloy with Cr/NiCr multilayer composite coating was only about 0.08 g/m2.h.

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王彥峰,李爭顯. NiCr涂層結構對Nb-1Zr合金抗氧化性能的影響[J].稀有金屬材料與工程,2017,46(7):1966~1971.[Wang Yanfeng, Li Zhengxian. Effects of NiCr coatings’ microstructure on oxidation resistance of Nb-1Zr alloys[J]. Rare Metal Materials and Engineering,2017,46(7):1966~1971.]
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  • 收稿日期:2016-03-30
  • 最后修改日期:2016-09-27
  • 錄用日期:2016-10-18
  • 在線發(fā)布日期: 2017-11-14
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