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FeWB基陶瓷在真空燒結(jié)過程中的組織和相轉(zhuǎn)變
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四川大學(xué)材料科學(xué)與工程學(xué)院,四川大學(xué)材料科學(xué)與工程學(xué)院,四川大學(xué)材料科學(xué)與工程學(xué)院,四川大學(xué)材料科學(xué)與工程學(xué)院

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Synthesis and microstructure evolution of FeWB based cermets during the vacuum sintering
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Sichuan University,,,

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    摘要:

    研究了燒結(jié)溫度和保溫時(shí)間對(duì)反應(yīng)硼化燒結(jié)制備FeWB基陶瓷的影響。利用X射線衍射,掃描電鏡和能譜儀對(duì)FeWB基燒結(jié)過程中的相轉(zhuǎn)變,微觀組織以及反應(yīng)機(jī)理進(jìn)行了表征。結(jié)果表明FeWB硬質(zhì)相是通過W + Fe2B = FeWB + Fe和FeB + W = FeWB兩種方式合成的,并且反應(yīng)生成的FeWB晶粒呈各向異性分布。在溫度區(qū)間為800℃-1150℃之間,F(xiàn)eWB基陶瓷的密度驟然升高,這與Fe2B相的熔化有關(guān)。在1300℃時(shí),由于W2B相的存在,會(huì)使FeWB相轉(zhuǎn)變?yōu)镕e7W6相,從而使密度進(jìn)一步升高。隨著燒結(jié)溫度的提高,通過液相燒結(jié)制備的金屬陶瓷表現(xiàn)出相對(duì)均勻的微觀結(jié)構(gòu),而且原位合成的FeWB顆粒會(huì)發(fā)生長(zhǎng)大。為了獲得較高的致密度,實(shí)驗(yàn)結(jié)果表明,F(xiàn)eWB基陶瓷的燒結(jié)溫度應(yīng)控制在1150℃-1250℃之間。其次,適當(dāng)?shù)脑黾予F和硼鐵的含量有利于燒結(jié)的致密化。

    Abstract:

    The FeWB based cermets were produced by the reaction boronizing sintering at different temperature and with different holding time. The influences of temperature and holding time on the phase transformation, microstructure of cermets as well as the reaction mechanism were investigated by X-ray diffraction meter (XRD), scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS). The results showed that the hard phase FeWB was produced in the compact at the stage of solid phase sintering by the reaction W + Fe2B = FeWB +Fe and W + FeB = FeWB. Besides, the FeWB phase exhibited an equiaxed morphology. The distinctly rapid densification occurred at the temperature ranging from 800°C to 1150°C while the FeWB phase transformed to Fe7W6 phase, which resulted in the further improvement of the density when the temperature exceeded 1300°C. With an increase of temperature, the cermets prepared by liquid phase sintering exhibited a relatively homogenous microstructure, accompanied by in situ growth of thick FeWB grains. In order to obtain a higher density, the experimental results showed that the sintering temperature of preparing FeWB based cermets should be controlled between 1150°C and 1250°C. Moreover, it was necessary to appropriately increase the content of iron and ferro-boron.

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余虹位,李軍,李程,劉穎. FeWB基陶瓷在真空燒結(jié)過程中的組織和相轉(zhuǎn)變[J].稀有金屬材料與工程,2018,47(2):463~468.[Hongwei Yu, Jun Li, Cheng Li, Ying Liu. Synthesis and microstructure evolution of FeWB based cermets during the vacuum sintering[J]. Rare Metal Materials and Engineering,2018,47(2):463~468.]
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  • 收稿日期:2016-03-10
  • 最后修改日期:2016-06-03
  • 錄用日期:2016-06-27
  • 在線發(fā)布日期: 2018-03-15
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