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Zr-Cu和Zr-Ni金屬玻璃中混合焓對(duì)β弛豫的影響
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西北有色金屬研究院,中國(guó)科學(xué)院物理研究所,西北有色金屬研究院,西北有色金屬研究院,西北有色金屬研究院,西北有色金屬研究院,西北有色金屬研究院,西北有色金屬研究院

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國(guó)家自然科學(xué)基金資助(項(xiàng)目號(hào)50921091)


The effect of mixing enthalpy on the β-relaxation in Zr-Cu and Zr-Ni metallic glasses
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Northwest Institute for Nonferrous Metal Research,Xi’an,Institute of Physics,Chinese Academy of Science,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an

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    摘要:

    β弛豫是金屬玻璃中重要的動(dòng)力學(xué)過(guò)程,但是β弛豫的結(jié)構(gòu)起源尚不清楚。本文研究了β弛豫與混合焓的關(guān)聯(lián)性,并從局域結(jié)構(gòu)的角度對(duì)這種關(guān)聯(lián)性進(jìn)行了解釋。針對(duì)Zr-Cu和Zr-Ni金屬玻璃,進(jìn)行了動(dòng)態(tài)力學(xué)分析和分子動(dòng)力學(xué)模擬,結(jié)果表明較大負(fù)值的混合焓有利于體系中二十面體團(tuán)簇的形成,而這種具有較高動(dòng)力學(xué)穩(wěn)定性的二十面體團(tuán)簇對(duì)β弛豫過(guò)程中的原子運(yùn)動(dòng)具有一定的抑制作用。

    Abstract:

    The β-relaxation is the principal source of the dynamics in glassy state, but the structural origin of β-relaxation is still not well understood. Here, the correlation between the β-relaxation and mixing enthalpy was studied, and the chemical effect is interpreted from the aspect of local structure. The dynamic mechanical measurements and molecular dynamics simulation of local structure were performed for Zr-Cu and Zr-Ni metallic glasses, which indicates the smaller negative mixing enthalpy facilitates the formation of the icosahedral clusters, and atom motion related to the β-relaxation is hindered by icosahedral clusters with high dynamic stability.

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高選喬,白海洋,郭林江,任廣鵬,薛建嶸,殷 濤,胡忠武,李來(lái)平. Zr-Cu和Zr-Ni金屬玻璃中混合焓對(duì)β弛豫的影響[J].稀有金屬材料與工程,2016,45(9):2293~2296.[Gao Xuanqiao, Bai Haiyang, Guo Linjiang, Ren Guangpeng, Xue Jianrong, Yin Tao, Hu Zhongwu, Li Laiping. The effect of mixing enthalpy on the β-relaxation in Zr-Cu and Zr-Ni metallic glasses[J]. Rare Metal Materials and Engineering,2016,45(9):2293~2296.]
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  • 收稿日期:2016-02-23
  • 最后修改日期:2016-04-14
  • 錄用日期:2016-04-26
  • 在線發(fā)布日期: 2016-10-09
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