13氫化物目前被認(rèn)為是最具有應(yīng)用前景的室溫磁制冷材料之一,對于主動式磁蓄冷制冷機(jī)而言,理想的磁制冷工質(zhì)為平行排列的片狀塊體。本工作在壓強(qiáng)高達(dá)40MPa的高壓氫氣氣氛下燒結(jié)制備了不同顆粒尺寸的厚度為0.8mm的片狀LaFe11.44Si1.56氫化物塊體,研究了顆粒尺寸及高壓燒結(jié)時(shí)間對氫化物塊體的結(jié)構(gòu)及磁熱效應(yīng)的影響。和母合金相比,燒結(jié)樣品的α-Fe含量有明顯增加,而燒結(jié)時(shí)間和顆粒尺寸對α-Fe析出沒有顯著影響。燒結(jié)樣品的居里溫度在室溫以上,并且隨著顆粒尺寸和燒結(jié)時(shí)間的增加而稍有增加。同時(shí),與母合金相比,燒結(jié)塊體中的磁滯顯著降低,這可以歸因于較小的顆粒尺寸和樣品中存在大量的微觀孔洞,降低了相變過程中的內(nèi)應(yīng)力。與顆粒尺寸為110~150μm的樣品相比,顆粒尺寸小于40μm的片狀塊體在磁熵變幾乎保持不變的基礎(chǔ)上,磁滯顯著降低35%。在0~1.5T的外磁場下其磁熵變和體積磁熵變在345K達(dá)到最大值8.5J/kg.K和53mJ/cm3.K。"/>

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高壓燒結(jié)時(shí)間及顆粒尺寸對片狀LaFe11.44Si1.56氫化物塊體結(jié)構(gòu)及磁熱效應(yīng)的影響
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沈陽理工大學(xué),沈陽理工大學(xué),沈陽理工大學(xué),沈陽理工大學(xué),沈陽理工大學(xué)

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國家自然科學(xué)基金資助(項(xiàng)目號51261001); 遼寧省自然科學(xué)資助(項(xiàng)目號2013020105);沈陽市科學(xué)計(jì)劃項(xiàng)目資助(項(xiàng)目號F13-316-1-39)


Effect of Particle Size and Sintering Duration on the Structure and Magnetocaloric Effect of Plate-shaped LaFe11.44Si1.56 Hydrides in High-pressure H2 Atmosphere
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Shenyang Ligong University,Shenyang Ligong University,Shenyang Ligong University,Shenyang Ligong University,Shenyang Ligong University

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    摘要:

    La(Fe,Si)13氫化物目前被認(rèn)為是最具有應(yīng)用前景的室溫磁制冷材料之一,對于主動式磁蓄冷制冷機(jī)而言,理想的磁制冷工質(zhì)為平行排列的片狀塊體。本工作在壓強(qiáng)高達(dá)40MPa的高壓氫氣氣氛下燒結(jié)制備了不同顆粒尺寸的厚度為0.8mm的片狀LaFe11.44Si1.56氫化物塊體,研究了顆粒尺寸及高壓燒結(jié)時(shí)間對氫化物塊體的結(jié)構(gòu)及磁熱效應(yīng)的影響。和母合金相比,燒結(jié)樣品的α-Fe含量有明顯增加,而燒結(jié)時(shí)間和顆粒尺寸對α-Fe析出沒有顯著影響。燒結(jié)樣品的居里溫度在室溫以上,并且隨著顆粒尺寸和燒結(jié)時(shí)間的增加而稍有增加。同時(shí),與母合金相比,燒結(jié)塊體中的磁滯顯著降低,這可以歸因于較小的顆粒尺寸和樣品中存在大量的微觀孔洞,降低了相變過程中的內(nèi)應(yīng)力。與顆粒尺寸為110~150μm的樣品相比,顆粒尺寸小于40μm的片狀塊體在磁熵變幾乎保持不變的基礎(chǔ)上,磁滯顯著降低35%。在0~1.5T的外磁場下其磁熵變和體積磁熵變在345K達(dá)到最大值8.5J/kg.K和53mJ/cm3.K。

    Abstract:

    La(Fe,Si)13 hydride is regarded as one of the most promising room-temperature magnetic refrigerants. A typical active magnetic refrigerator machine requires thin plate-shaped refrigerants. In this work, plate-shaped LaFe11.44Si1.56 hydrides with different particle sizes were prepared by sintering in a high-pressure H2 atmosphere of 40MPa. Effect of particle size and sintering duration on the structure and magnetocaloric effect was investigated. Compared to the parent alloy, α-Fe contents of the sintered samples are increased and different particle sizes and sintering duration do not remarkably influence the precipitation of α-Fe. Upon increasing of particle size, Curie temperatures of sintered samples slightly increase and are shifted to above room temperature. Hysteresis of plate-shaped LaFe11.44Si1.56 hydrides has been almost eliminated due to the existence of micropores with a large size of distribution and small particle size, which reduces the internal strain during the process of the phase transitions. Compared with the sintered sample with particle size from 110 to 150μm, the hysteresis loss of the sintered sample with particle size smaller than 40μm is decreased by 35%, while the large magnetic-entropy ΔSm maintains. LaFe11.44Si1.56 thin plate-shaped hydride with particle size smaller than 40μm exhibits a large change ΔSm of 8.5J/kg.K(53mJ/cm3.K) for a field change of 1.5T at 345K.

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佟永麗,郭杰,任增鑫,徐志潔,孫乃坤.高壓燒結(jié)時(shí)間及顆粒尺寸對片狀LaFe11.44Si1.56氫化物塊體結(jié)構(gòu)及磁熱效應(yīng)的影響[J].稀有金屬材料與工程,2018,47(3):954~960.[Tong Yongli, Guo Jie, Ren Zengxin, Xu Zhijie, Sun Naikun. Effect of Particle Size and Sintering Duration on the Structure and Magnetocaloric Effect of Plate-shaped LaFe11.44Si1.56 Hydrides in High-pressure H2 Atmosphere[J]. Rare Metal Materials and Engineering,2018,47(3):954~960.]
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  • 收稿日期:2016-01-28
  • 最后修改日期:2016-05-24
  • 錄用日期:2016-06-12
  • 在線發(fā)布日期: 2018-04-11
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