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長期時(shí)效對一種鎳基合金的組織與性能影響
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鋼鐵研究總院特殊鋼研究所,鋼鐵研究總院特殊鋼研究所,鋼鐵研究總院特殊鋼研究所,湖南人文科技學(xué)院,鋼鐵研究總院特殊鋼研究所,鋼鐵研究總院特殊鋼研究所

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TG132.3

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國家863項(xiàng)目(2012AA03A502)


Effects of long-term aging on microstructure and properties of a nickel-base alloy
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Institute for Special Steels,Central Iron and Steel Research Institute,Institute for Special Steels,Central Iron and Steel Research Institute,Institute for Special Steels,Central Iron and Steel Research Institute,Hunan University of Humanities,Science and Technology,Institute for Special Steels,Central Iron and Steel Research Institute,Institute for Special Steels,Central Iron and Steel Research Institute

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    摘要:

    研究了一種鎳基合金USC141在700℃長期時(shí)效過程中組織與性能的變化。研究結(jié)果表明,隨時(shí)效時(shí)間延長,合金的室、高溫強(qiáng)度一直保持在較高水平,而晶界碳化物的長大粗化以及逐漸連續(xù)成鏈狀,會(huì)使得合金的塑性和韌性逐漸下降。時(shí)效過程中,合金中M23C6的析出量緩慢增加,而合金中M6C型碳化物的演變過程包括三個(gè)階段:①M(fèi)6C→M12C轉(zhuǎn)變階段,主要由Mo和Ni元素的擴(kuò)散進(jìn)入引起,碳化物總量顯著增加; ②碳化物穩(wěn)定階段,碳化物類型以及析出量變化不大;③ M12C進(jìn)一步析出、粗化階段,主要由Mo元素的擴(kuò)散進(jìn)入引起,晶內(nèi)新析出呈薄片狀的M12C碳化物。合金中的γ′相的析出行為也包括三個(gè)階段:① γ′相快速析出長大階段,同時(shí)顆粒大小趨于均勻化;② γ′相緩慢析出長大階段,γ′相的尺寸和析出量緩慢增加;③ γ′相粗化、融合階段,相鄰較小尺寸的γ′顆粒接觸后融合成較大尺寸γ′顆粒,使得部分γ′相顆粒明顯粗化以及總體顆粒尺寸的分布散度顯著增加。

    Abstract:

    It was investigated that the microstructure and mechanical property evolution of a supperalloy USC 141 under aging 10000h at 700oC in this paper. The results show that both of the strengths of the alloy tested at room temperature and 700oC were maintained at high level during long-term aging, while the coarsening behavior of carbides along grain boundary, which transformed in a shape of chain generally, leads to decrease plasticity and toughness. During the process of long-term aging,the precipitation of M23C6 showed a trend of slow increasing. Whereas the evolution of M6C type carbide in this alloy consists of three stages. The first stage could be marked as the continuum transformation of M6C to M12C, which was induced by the diffusion of Mo and Ni. At the second stage, the carbide type and the precipitation of carbides changed little. At the third stage, M12C carbides further coarsened afterwards by the diffusion of Mo, and M12C inside grains shows a shape of plate. The microstructure evolution of γ′ precipitates could be divided into three stages as well. The formation and initial grow up fastly of γ′ was resulted from the diffusion of Cr, and the γ′ particles were distributed finely during the first stage. At the second stage, the means size and precipitation of γ′ increase slowly. The last stage was marked by the coarsening behavior of γ′, mainly resulting from the coalescence of adjacent γ′ particles, and finally exhibited higher dispersion level of particle size distribution.

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引用本文

王魯,楊鋼,劉正東,汪力,馬龍騰,楊志強(qiáng).長期時(shí)效對一種鎳基合金的組織與性能影響[J].稀有金屬材料與工程,2018,47(3):961~967.[WANG Lu, YANG Gang, LIU Zhen-dong, WANG Li, MA Longteng, YANG Zhiqiang. Effects of long-term aging on microstructure and properties of a nickel-base alloy[J]. Rare Metal Materials and Engineering,2018,47(3):961~967.]
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  • 收稿日期:2016-01-20
  • 最后修改日期:2016-04-21
  • 錄用日期:2016-05-19
  • 在線發(fā)布日期: 2018-04-11
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