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基于兩步法陽極氧化的TiO2納米管陣列制備研究
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國家自然科學(xué)基金 (51205275, 51205276);山西省科技研究基金 (2013021017-1, 20141001021-2);國家“863”計(jì)劃項(xiàng)目(2013AA041100);山西省科技重大專項(xiàng) (20121101004);山西省高等特色學(xué)科建設(shè) ([2012]45) 資助項(xiàng)目;山西省人社廳留學(xué)人員科技活動(dòng)項(xiàng)目擇優(yōu)資助 (143050103-S);山西省人社部留學(xué)人員科技活動(dòng)項(xiàng)目擇優(yōu)資助 (153050010-C)


Fabrication of TiO2 Nanotube Arrays by Two-step Anodic Oxidation
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    摘要:

    采用低濃度的無機(jī)溶劑HF溶液(0.05%, 質(zhì)量分?jǐn)?shù))對濺射在硅基底上的400 nm鈦薄膜進(jìn)行陽極氧化制備TiO2納米管陣列,并利用SEM對制備出的TiO2納米管陣列進(jìn)行表征。實(shí)驗(yàn)結(jié)果表明,通過優(yōu)化陽極氧化電壓幅值、電壓施加方式和氧化時(shí)間,均可有效控制納米管陣列的尺寸和形貌。首先施加0.5 V的低電壓28 min,在低濃度的HF溶液中陽極氧化鈦薄膜制備TiO2納米管陣列,其管徑可達(dá)120 nm左右。在此基礎(chǔ)上,對電壓施加方式進(jìn)行改進(jìn),提出兩步法施加電壓方式,并優(yōu)化氧化時(shí)間,在硅基底鈦薄膜上制備出管徑為100 ~ 270 nm結(jié)構(gòu)緊密有序的TiO2納米管陣列,明顯優(yōu)于鈦薄膜在有機(jī)電解液中氧化制備的管徑為70 ~ 100 nm的TiO2納米管陣列

    Abstract:

    TiO2 nanotube arrays were fabricated on Si substrate in HF solution with the low concentration of 0.05 wt%. The diameter and the morphology of the TiO2 nanotubes were observed by scanning electronic microscope (SEM). The effects of oxidation voltage and the applying way of voltage on the nanotubes morphology were investigated. The results show that the diameter and the morphology of the TiO2 nanotubes are obviously influenced by the parameters of the oxidation condition. The TiO2 nanotubes with diameters of 120 nm are obtained by applying a voltage of 0.5 V for 28 min in HF solution with the low concentration of 0.05 wt%. The diameter of the nanotubes could be enlarged to a larger range by optimizing the oxidation time. The dense TiO2 nanotubes with diameters ranging from about 100 to 270 nm are fabricated by the two-step anodic oxidation method, which are much better than the TiO2 nanotubes with diameters from about 70 to 100 nm obtained in the organic electrolyte

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張君慧,郭麗芳,趙清華,張文棟,李大維,李 剛,孫 偉.基于兩步法陽極氧化的TiO2納米管陣列制備研究[J].稀有金屬材料與工程,2015,44(12):3136~3140.[Zhang Junhui, Guo Lifang, Zhao Qinghua, Zhang Wendong, Li Dawei, Li Gang, Sun Wei. Fabrication of TiO2 Nanotube Arrays by Two-step Anodic Oxidation[J]. Rare Metal Materials and Engineering,2015,44(12):3136~3140.]
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  • 收稿日期:2014-12-10
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  • 在線發(fā)布日期: 2016-08-29
  • 出版日期: 2015-12-25