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Synthesis and Refinement Performance of the Novel Al-Ti-B-RE Master Alloy Grain Refiner
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Synthesis and Refinement Performance of the Novel Al-Ti-B-RE Master Alloy Grain Refiner
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Natural Science Foundation of Jiangsu Province of China (BK2011524); Natural Science Foundation of Education Department of Jiangsu Province of China (12KJD430002); Project Supported by Graduate Research and Innovation of Jiangsu University in 2014, Jiangsu Province, China (KYXX_0001)

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    摘要:

    為優(yōu)化鋁中間合金細化劑的組織,提升細化性能,采用熔配法工藝合成新型Al-Ti-B-RE中間合金晶粒細化劑,合成反應基于熱力學和動力學分析是可能的、存在的、自發(fā)向右進行,在適當?shù)墓に嚄l件下,在基體中可生成均勻彌散分布的第二相A13Ti、TiB2、Ti2A120RE等粒子。采用X射線衍射(XRD)、掃描電鏡(SEM)、光學顯微鏡(OM)和力學拉伸試驗等分析方法對所合成材料的微觀組織、細化效果及力學性能進行了表征。細化試驗表明:自制的Al-5Ti-1B-1RE中間合金細化工業(yè)純鋁時,其平均晶粒尺寸小于150 μm到達細晶粒度級別。拉伸試驗表明:工業(yè)純鋁中加入0.2%自制的Al-5Ti-1B-1RE中間合金晶粒細化劑后有更優(yōu)的機械性能,與未細化工業(yè)純鋁相比,抗拉強度提高了28.39 MPa,延伸率增加了29.97%,其性能明顯優(yōu)于某國產(chǎn)的Al-5Ti-1B絲中間合金細化劑

    Abstract:

    To obtain better microstructures, a new aluminum grain refiner, Al-Ti-B-RE master alloy, was synthesized by the mix-molten method. Analyzed by thermodynamics and kinetics, the synthesis reactions of Al-Ti-B-RE master alloy would be possible, existent and to the right spontaneously. The second phase particles of the Al-Ti-B-RE master alloy mainly contained A13Ti, TiB2 and Ti2A120RE, etc. Under appropriate conditions, the second phase particles could be distributed homogeneously in the matrix. The morphology and the distribution of second phases of Al-Ti-B-RE master alloy, refining effects and mechanical properties were studied by XRD, SEM,OM and the electron all-purpose test machine (CSS-44100). The refinement experiment indicates that the self-made Al-5Ti-1B-1RE master alloy can refine the commercial pure aluminum into the level of the average grain size less than 150 μm, which belongs to the fine grain category. The tensile testing results show that after the addition of 0.2% self-made Al-5Ti-1B-1RE master alloy grain refiner into the commercial pure aluminum, the mechanical properties are improved significantly. Under the same condition, compared with the commercial pure aluminum without refinement, tensile strength σb and elongation δ are increased by 28.39 MPa and 29.97%, respectively. It is evident that the self-made Al-5Ti-1B-1RE master alloy grain refiner is superior to some domestic Al-5Ti-1B grain refiner

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王正軍,司乃潮. Synthesis and Refinement Performance of the Novel Al-Ti-B-RE Master Alloy Grain Refiner[J].稀有金屬材料與工程,2015,44(12):2970~2975.[Wang Zhengjun, Si Naichao. Synthesis and Refinement Performance of the Novel Al-Ti-B-RE Master Alloy Grain Refiner[J]. Rare Metal Materials and Engineering,2015,44(12):2970~2975.]
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  • 收稿日期:2014-11-14
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  • 在線發(fā)布日期: 2016-08-29
  • 出版日期: 2015-12-25