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Preparation of Ni-SiC Composite Coating by Electrochemical Deposition
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Preparation of Ni-SiC Composite Coating by Electrochemical Deposition
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National Natural Science Foundation of China (51101104, 51372156); Program for Liaoning Excellent Talents in University (LJQ2015074)

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    摘要:

    采用電化學(xué)沉積法通過在電解槽中添加SiC顆粒制備Ni-SiC復(fù)合鍍層。由于第二相顆粒SiC的加入改善了鍍層的性能,使之具有高硬度、耐磨性和耐腐蝕性能等。Ni-SiC復(fù)合電鍍改善鍍層的組織結(jié)構(gòu)并顯著提高鍍層的質(zhì)量。采用NiSO4·6H2O(35 g/100 mL),NiCl2·6H2O(4 g/100 mL),H3BO3(3.5 g/100 mL),十二烷基硫酸鈉(0.5 g/100 mL),SiC顆粒(0.4~1.0 g/100 mL)體系,在pH值為4,溫度35~50 ℃時,通過電化學(xué)沉積法制備Ni-SiC復(fù)合鍍層。實驗探究了溫度、電流密度、鍍液中碳化硅顆粒含量以及超聲波分散時間對鍍層中SiC復(fù)合量的影響。通過掃描電鏡和XRD對鍍層進行分析,結(jié)果表明:在溫度為35~50 ℃之間復(fù)合鍍層中SiC的量隨溫度的增加呈現(xiàn)先增加后減少的趨勢;在電流密度為0.026~0.06 A/cm2之間,復(fù)合鍍層中SiC的含量隨電流密度的增加呈現(xiàn)先增加后減小的趨勢;鍍液中SiC量在0.4~1.0 g/100 mL之間時,鍍層中SiC含量隨著鍍液中SiC含量的增加而增加,超過一定值(0.6 g/100 mL)增加幅度變?。怀暡ǚ稚r間在10~50 min之間, 鍍層中SiC的含量隨時間的增加而先增加后減少。鍍層中碳化硅顆粒均勻分布有利于晶粒的細化

    Abstract:

    Ni-SiC composite coating was electrodeposited from the modified bath containing SiC particles. The system consisting of NiSO4·6H2O (35 g/100 mL), NiCl2·6H2O (4 g/100 mL), H3BO3 (3.5 g/100 mL), sodium dodecyl sulfate (SDS) (0.5 g/100 mL) and SiC (0.4~1.0 g/100 mL) was used at pH=4 and 35~50 ℃ to obtain a Ni-based composite coating containing SiC particles. The effects of temperature, current density, content of SiC in the electrolyte and ultrasonic dispersion time on codeposited content of SiC particles were investigated. The Ni-SiC composite coating was characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The results indicate that the codeposited content of SiC particles increases with increasing of temperature and then decreases at 35~50 °C. When current density is between 0.026~ 0.06 A/cm2, SiC content increases with the increase of current density and then decreases. When the concentration of SiC is between 0.4~1.0 g/100 mL in the plating solution, it increases with the increase of concentration of SiC. When the content of SiC exceeds a certain value (0.6 g/100 mL), the rate increase becomes low. When the ultrasonic dispersion time is between 10~50 min, the codeposited content of SiC particles first increases and then decreases with increasing of time. Uniform distribution of SiC particles in the coating is beneficial to refine the grain size of deposit

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闞洪敏,楊兆一,張 寧. Preparation of Ni-SiC Composite Coating by Electrochemical Deposition[J].稀有金屬材料與工程,2015,44(12):2960~2964.[Kan Hongmin, Yang Zhaoyi, Zhang Ning. Preparation of Ni-SiC Composite Coating by Electrochemical Deposition[J]. Rare Metal Materials and Engineering,2015,44(12):2960~2964.]
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  • 收稿日期:2014-12-12
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  • 在線發(fā)布日期: 2016-08-29
  • 出版日期: 2015-12-25