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Ir(ppy)3分子的磷光發(fā)射溫度依賴和磁場增強效應
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Influence of Temperature and Magnetic Field on Phosphorescence from Ir(ppy)3
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    摘要:

    應用磁光光譜技術,測量并研究了溶解在四氫呋喃(tetrahydrofuran,THF)中Ir(ppy)3分子的磷光發(fā)射特性隨溫度和磁場的變化規(guī)律。發(fā)現在2.2 K時可見光波段Ir(ppy)3有兩個磷光發(fā)射峰,分別位于547.70和515.18 nm。這是由系統(tǒng)的金屬到配位體電荷轉移態(tài)(3MLCT)中兩個激發(fā)態(tài)到基態(tài)的光躍遷引起。改變溫度可以改變三重態(tài)中亞能級Ⅰ、Ⅱ和Ⅲ上的電子分布,使得磷光發(fā)射峰的強度在10 K時發(fā)生反轉,并且光譜發(fā)射強度在20~300 K間隨溫度增加而減弱。在強磁場作用下,Ir(ppy)3在2.2 K溫度下的磷光發(fā)射強度隨磁場強度增大而增強。外加磁場能改變3MLCT態(tài)的三個亞能級上的電子躍遷幾率,從而能增加磷光發(fā)射強度。

    Abstract:

    The basic features of phosphorescent emission from Ir(ppy)3 (ppy=2-phenylpyridinate), dissolved in THF, were investigated by a magneto-luminescence technique. It is found that there are two peaks in the phosphorescent spectra in visible region from 2.2~77 K. They are located at 547.70 nm and 515.70 nm wavelength. This is due to radiative electronic transition from two substates in 3MLCT structure to the ground state of Ir(ppy)3. Changing temperature can vary electron distribution and life-time on different substates in the 3MLCT structure of Ir(ppy)3. Thus, we can observe a strong dependence of the phosphorescent spectrum on temperature. Furthermore, we find that the intensity of phosphorescent emission from Ir(ppy)3 increases with magnetic field at 2.2 K. The presence of the high magnetic field can alter the electronic states and, thus, modulate the electron distribution and transition possibility for substates in 3MLCT. As a result, the phosphorescence emission from Ir(ppy)3 can be enhanced by the presence of the magnetic field.

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余書楷,張 超,蘇付海,徐 文. Ir(ppy)3分子的磷光發(fā)射溫度依賴和磁場增強效應[J].稀有金屬材料與工程,2015,44(11):2923~2926.[Yu Shukai, Zhang Chao, Su Fuhai, Xu Wen. Influence of Temperature and Magnetic Field on Phosphorescence from Ir(ppy)3[J]. Rare Metal Materials and Engineering,2015,44(11):2923~2926.]
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  • 收稿日期:2015-04-05
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  • 在線發(fā)布日期: 2016-07-29
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